Role of sonication pre-treatment and cation valence in the sol-gel transition of nano-cellulose suspensions

C. A. Maestri, M. Abrami, S. Hazan, E. Chistè, Y. Golan, J. Rohrer, A. Bernkop-Schnürch, M. Grassi, M. Scarpa, P. Bettotti

Research output: Contribution to journalArticlepeer-review

27 Scopus citations


Sol-gel transition of carboxylated cellulose nanocrystals has been investigated using rheology, SAXS, NMR and optical spectroscopies to unveil the distinctive roles of ultrasound treatments and addition of various cations. Besides cellulose fiber fragmentation, sonication treatment induces fast gelling of the solution. The gelation is independent of the addition of cations, while the final rheological properties are highly influenced by the type, concentration and sequence of the operations since the cations must be added prior to sonication to produce stiff gels. The gel elastic modulus was found to increase proportionally to the ionic charge rather than the cationic size. In cases where ions were added after sonication, SAXS analysis of the Na+ hydrogel and Ca2+ hydrogel indicated the presence of structurally ordered domains in which water is confined, and 1H-NMR investigation showed the dynamics of water exchange within the hydrogels. Conversely, separated phases containing essentially free water were characteristic of the hydrogels obtained by sonication after Ca2+ addition, confirming that this ion induces irreversible fiber aggregation. The rheological properties of the hydrogels depend on the duration of the ultrasound treatments, enabling the design of programmed materials with tailored energy dissipation response.

Original languageEnglish
Article number11129
JournalScientific Reports
Issue number1
StatePublished - 1 Dec 2017

ASJC Scopus subject areas

  • General


Dive into the research topics of 'Role of sonication pre-treatment and cation valence in the sol-gel transition of nano-cellulose suspensions'. Together they form a unique fingerprint.

Cite this