Rotational alignment and non-statistical a doublet population in no following (CH3)3CONO photodissociation

D. Schwartz-Lavi; I. Bar; S. Rosenwaks

doi:10.1016/0009-2614(86)80309-8

Rotational alignment and non-statistical a doublet population in no following (CH₃)₃CONO photodissociation

D. Schwartz-Lavi, I. Bar, S. Rosenwaks

Department of Physics

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37 Scopus citations

Abstract

The rotational alignment and internal state distribution of the NO fragment ejected from the photodissociation of (CH₃)₃CONO in its first absorption band are determined. The rotational distribution is non-Boltzmann and unaffected by the dissociating wavelength. The NO fragment is rotationally aligned and the Π^- antisymmetric. Λ doublet component is preferentially populated, indicating planarity of the fragmentation process.

Original language	English
Pages (from-to)	123-126
Number of pages	4
Journal	Chemical Physics Letters
Volume	128
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(86)80309-8
State	Published - 18 Jul 1986

ASJC Scopus subject areas

Physics and Astronomy (all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(86)80309-8

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title = "Rotational alignment and non-statistical a doublet population in no following (CH3)3CONO photodissociation",

abstract = "The rotational alignment and internal state distribution of the NO fragment ejected from the photodissociation of (CH3)3CONO in its first absorption band are determined. The rotational distribution is non-Boltzmann and unaffected by the dissociating wavelength. The NO fragment is rotationally aligned and the Π- antisymmetric. Λ doublet component is preferentially populated, indicating planarity of the fragmentation process.",

author = "D. Schwartz-Lavi and I. Bar and S. Rosenwaks",

year = "1986",

month = jul,

day = "18",

doi = "10.1016/0009-2614(86)80309-8",

language = "English",

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journal = "Chemical Physics Letters",

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T1 - Rotational alignment and non-statistical a doublet population in no following (CH3)3CONO photodissociation

AU - Schwartz-Lavi, D.

AU - Bar, I.

AU - Rosenwaks, S.

PY - 1986/7/18

Y1 - 1986/7/18

N2 - The rotational alignment and internal state distribution of the NO fragment ejected from the photodissociation of (CH3)3CONO in its first absorption band are determined. The rotational distribution is non-Boltzmann and unaffected by the dissociating wavelength. The NO fragment is rotationally aligned and the Π- antisymmetric. Λ doublet component is preferentially populated, indicating planarity of the fragmentation process.

AB - The rotational alignment and internal state distribution of the NO fragment ejected from the photodissociation of (CH3)3CONO in its first absorption band are determined. The rotational distribution is non-Boltzmann and unaffected by the dissociating wavelength. The NO fragment is rotationally aligned and the Π- antisymmetric. Λ doublet component is preferentially populated, indicating planarity of the fragmentation process.

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U2 - 10.1016/0009-2614(86)80309-8

DO - 10.1016/0009-2614(86)80309-8

M3 - Article

AN - SCOPUS:0000835779

SN - 0009-2614

VL - 128

SP - 123

EP - 126

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Rotational alignment and non-statistical a doublet population in no following (CH₃)₃CONO photodissociation

Abstract

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