Ruthenium-catalyzed dimerization of propiolates: A simple route to α-pyrones

Rajendran Manikandan, Masilamani Jeganmohan

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

A ruthenium-catalyzed regioselective intermolecular multistep homo- and heterodimerization of substituted propiolates providing α-pyrone-5- carboxylates and α-pyrone-6-carboxylates is described. The synthetic utilities of α-pyrone derivatives are shown. The proposed mechanism is strongly supported by experimental evidence.

Original languageEnglish
Pages (from-to)652-655
Number of pages4
JournalOrganic Letters
Volume16
Issue number3
DOIs
StatePublished - 7 Feb 2014
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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