Second stage physintcrcalation of N2 molecules into C24Rb

H. Shaked; R. Moreh; H. Pinto; M. Melamud; Y. Finkelstein

doi:10.1080/10587259808045322

Second stage physintcrcalation of N₂ molecules into C₂₄Rb

H. Shaked, R. Moreh, H. Pinto, M. Melamud, Y. Finkelstein

Department of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Using neutron diffraction, a second stage physintercalation of molecular N₂ into C₂₄Rb has been observed in which the N₂ molecules reside inside every second Rb layer. The new phase, C₄₈Rb₂(N₂)_x, coexists below 175 K with pure C24Rb and the 1st stage C₂₄Rb(N₂)_x. The tilt of the N₂ molecular axes relative to the graphene planes was determined versus T using the nuclear resonance photon scattering (NRPS) technique and found to be almost parallel to the graphene planes of the C₂₄Rb sample.

Original language	English
Pages (from-to)	105-110
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	310
DOIs	https://doi.org/10.1080/10587259808045322
State	Published - 1 Jan 1998

Keywords

CRb
Graphite intercalation compounds
Molecular orientation
N adsorption
n-diffraction
γ-ray resonance scattering

ASJC Scopus subject areas

Condensed Matter Physics

Access to Document

10.1080/10587259808045322

Cite this

@article{3d3dc2209fc045fe917af85365b56670,

title = "Second stage physintcrcalation of N2 molecules into C24Rb",

abstract = "Using neutron diffraction, a second stage physintercalation of molecular N2 into C24Rb has been observed in which the N2 molecules reside inside every second Rb layer. The new phase, C48Rb2(N2)x, coexists below 175 K with pure C24Rb and the 1st stage C24Rb(N2)x. The tilt of the N2 molecular axes relative to the graphene planes was determined versus T using the nuclear resonance photon scattering (NRPS) technique and found to be almost parallel to the graphene planes of the C24Rb sample.",

keywords = "CRb, Graphite intercalation compounds, Molecular orientation, N adsorption, n-diffraction, γ-ray resonance scattering",

author = "H. Shaked and R. Moreh and H. Pinto and M. Melamud and Y. Finkelstein",

note = "Funding Information: This work was supported by the German-Israeli Foundation for Scientific Research and Development (G.I.F.).",

year = "1998",

month = jan,

day = "1",

doi = "10.1080/10587259808045322",

language = "English",

volume = "310",

pages = "105--110",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Second stage physintcrcalation of N2 molecules into C24Rb

AU - Shaked, H.

AU - Moreh, R.

AU - Pinto, H.

AU - Melamud, M.

AU - Finkelstein, Y.

N1 - Funding Information: This work was supported by the German-Israeli Foundation for Scientific Research and Development (G.I.F.).

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Using neutron diffraction, a second stage physintercalation of molecular N2 into C24Rb has been observed in which the N2 molecules reside inside every second Rb layer. The new phase, C48Rb2(N2)x, coexists below 175 K with pure C24Rb and the 1st stage C24Rb(N2)x. The tilt of the N2 molecular axes relative to the graphene planes was determined versus T using the nuclear resonance photon scattering (NRPS) technique and found to be almost parallel to the graphene planes of the C24Rb sample.

AB - Using neutron diffraction, a second stage physintercalation of molecular N2 into C24Rb has been observed in which the N2 molecules reside inside every second Rb layer. The new phase, C48Rb2(N2)x, coexists below 175 K with pure C24Rb and the 1st stage C24Rb(N2)x. The tilt of the N2 molecular axes relative to the graphene planes was determined versus T using the nuclear resonance photon scattering (NRPS) technique and found to be almost parallel to the graphene planes of the C24Rb sample.

KW - CRb

KW - Graphite intercalation compounds

KW - Molecular orientation

KW - N adsorption

KW - n-diffraction

KW - γ-ray resonance scattering

UR - http://www.scopus.com/inward/record.url?scp=0031642611&partnerID=8YFLogxK

U2 - 10.1080/10587259808045322

DO - 10.1080/10587259808045322

M3 - Article

AN - SCOPUS:0031642611

SN - 1058-725X

VL - 310

SP - 105

EP - 110

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -