Abstract
Using neutron diffraction, a second stage physintercalation of molecular N2 into C24Rb has been observed in which the N2 molecules reside inside every second Rb layer. The new phase, C48Rb2(N2)x, coexists below 175 K with pure C24Rb and the 1st stage C24Rb(N2)x. The tilt of the N2 molecular axes relative to the graphene planes was determined versus T using the nuclear resonance photon scattering (NRPS) technique and found to be almost parallel to the graphene planes of the C24Rb sample.
| Original language | English |
|---|---|
| Pages (from-to) | 105-110 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals |
| Volume | 310 |
| DOIs | |
| State | Published - 1 Jan 1998 |
Keywords
- CRb
- Graphite intercalation compounds
- Molecular orientation
- N adsorption
- n-diffraction
- γ-ray resonance scattering
ASJC Scopus subject areas
- Condensed Matter Physics
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