Abstract
The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.
Original language | English |
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Pages (from-to) | 688-690 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 22 |
Issue number | 4 |
DOIs | |
State | Published - 1 Jan 1983 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry