Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen, Shlomo Efrima, Dan Meyerstein, Mordechi Nutkovich, Karl Wieghardt

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

Original languageEnglish
Pages (from-to)688-690
Number of pages3
JournalInorganic Chemistry
Volume22
Issue number4
DOIs
StatePublished - 1 Jan 1983

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