Self-assembly of conducting cocrystals: Via iodine⋯π(Cp) interactions

Yury V. Torubaev; Konstantin A. Lyssenko; Petro Y. Barzilovich; George A. Saratov; Mobin M. Shaikh; Ajeet Singh; Pradeep Mathur

doi:10.1039/c7ce00857k

Self-assembly of conducting cocrystals: Via iodine⋯π(Cp) interactions

Yury V. Torubaev, Konstantin A. Lyssenko, Petro Y. Barzilovich, George A. Saratov, Mobin M. Shaikh, Ajeet Singh, Pradeep Mathur

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Conducting crystals of alternating ferrocene and diiodoacetylene units assembled into supramolecular 1-D chains via I⋯π(Cp) halogen bonds were prepared and structurally characterized. Their structure and conductivity were compared with the ferrocene cocrystals with phenyliodoacetylene (C₆H₅C₂I) and 1,4-di(ethynyliodo)phenylene. Electrical conductivity measurements of the ferrocene-based cocrystals revealed comparatively high electron-hole type conductivity in the ferrocene (FcH)-diiodoacetylene (C₂I₂) pair, a 3-order decrease in combination with the 1,4-di(ethynyliodo)phenylene linker, and it is virtually extinguished with the monotopic 1,2-phenyliodoacetylene. The increased electric conductivity of compound 1 is rationalized in terms of a weak charge transfer through the I⋯πCp halogen bonds in the [Cp-Fe-Cp⋯I-CC-I⋯]_n polymeric chains.

Original language	English
Pages (from-to)	5114-5121
Number of pages	8
Journal	CrystEngComm
Volume	19
Issue number	34
DOIs	https://doi.org/10.1039/c7ce00857k
State	Published - 1 Jan 2017
Externally published	Yes

ASJC Scopus subject areas

Chemistry (all)
Materials Science (all)
Condensed Matter Physics

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@article{e0ffb028458a450688069ef15e0e1228,

title = "Self-assembly of conducting cocrystals: Via iodine⋯π(Cp) interactions",

abstract = "Conducting crystals of alternating ferrocene and diiodoacetylene units assembled into supramolecular 1-D chains via I⋯π(Cp) halogen bonds were prepared and structurally characterized. Their structure and conductivity were compared with the ferrocene cocrystals with phenyliodoacetylene (C6H5C2I) and 1,4-di(ethynyliodo)phenylene. Electrical conductivity measurements of the ferrocene-based cocrystals revealed comparatively high electron-hole type conductivity in the ferrocene (FcH)-diiodoacetylene (C2I2) pair, a 3-order decrease in combination with the 1,4-di(ethynyliodo)phenylene linker, and it is virtually extinguished with the monotopic 1,2-phenyliodoacetylene. The increased electric conductivity of compound 1 is rationalized in terms of a weak charge transfer through the I⋯πCp halogen bonds in the [Cp-Fe-Cp⋯I-CC-I⋯]n polymeric chains.",

author = "Torubaev, {Yury V.} and Lyssenko, {Konstantin A.} and Barzilovich, {Petro Y.} and Saratov, {George A.} and Shaikh, {Mobin M.} and Ajeet Singh and Pradeep Mathur",

note = "Funding Information: We thank the Russian Foundation for Basic Research (projects 16-03-00798, 16-29-09368) and the Department of Science and Technology, Government of India for the financial support of this work. Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

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doi = "10.1039/c7ce00857k",

language = "English",

volume = "19",

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T1 - Self-assembly of conducting cocrystals

T2 - Via iodine⋯π(Cp) interactions

AU - Torubaev, Yury V.

AU - Lyssenko, Konstantin A.

AU - Barzilovich, Petro Y.

AU - Saratov, George A.

AU - Shaikh, Mobin M.

AU - Singh, Ajeet

AU - Mathur, Pradeep

N1 - Funding Information: We thank the Russian Foundation for Basic Research (projects 16-03-00798, 16-29-09368) and the Department of Science and Technology, Government of India for the financial support of this work. Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Conducting crystals of alternating ferrocene and diiodoacetylene units assembled into supramolecular 1-D chains via I⋯π(Cp) halogen bonds were prepared and structurally characterized. Their structure and conductivity were compared with the ferrocene cocrystals with phenyliodoacetylene (C6H5C2I) and 1,4-di(ethynyliodo)phenylene. Electrical conductivity measurements of the ferrocene-based cocrystals revealed comparatively high electron-hole type conductivity in the ferrocene (FcH)-diiodoacetylene (C2I2) pair, a 3-order decrease in combination with the 1,4-di(ethynyliodo)phenylene linker, and it is virtually extinguished with the monotopic 1,2-phenyliodoacetylene. The increased electric conductivity of compound 1 is rationalized in terms of a weak charge transfer through the I⋯πCp halogen bonds in the [Cp-Fe-Cp⋯I-CC-I⋯]n polymeric chains.

AB - Conducting crystals of alternating ferrocene and diiodoacetylene units assembled into supramolecular 1-D chains via I⋯π(Cp) halogen bonds were prepared and structurally characterized. Their structure and conductivity were compared with the ferrocene cocrystals with phenyliodoacetylene (C6H5C2I) and 1,4-di(ethynyliodo)phenylene. Electrical conductivity measurements of the ferrocene-based cocrystals revealed comparatively high electron-hole type conductivity in the ferrocene (FcH)-diiodoacetylene (C2I2) pair, a 3-order decrease in combination with the 1,4-di(ethynyliodo)phenylene linker, and it is virtually extinguished with the monotopic 1,2-phenyliodoacetylene. The increased electric conductivity of compound 1 is rationalized in terms of a weak charge transfer through the I⋯πCp halogen bonds in the [Cp-Fe-Cp⋯I-CC-I⋯]n polymeric chains.

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DO - 10.1039/c7ce00857k

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ER -

Self-assembly of conducting cocrystals: Via iodine⋯π(Cp) interactions

Abstract

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