Self-guided one-sided metal reduction in te nanowires leading to Au-te matchsticks

Highly anisotropic nanoscale structures are fundamentally important for understanding the properties of hybrid nanoscale systems and self-organization phenomena, but they are typically difficult to prepare experimentally. Hybrid Au and Tematchstick-like nanostructures, which display high structural anisotropy, were synthesized using small Au clusters as seeds. Thematchsticks were found to be an exclusive product of this reaction.Wehypothesize that themechanismof the synthesis is based on self-directed site-specific reduction of Au ions due to the gradually increasing dipole moment facilitating this process on one side of Te nanorods, which is supported by quantum mechanical calculations.