Sensitivity of an integrating differential pulse polarograph to interfering signals

Sam Ben-Yaakov; H. Guterman

doi:10.1016/S0022-0728(81)80322-1

Sensitivity of an integrating differential pulse polarograph to interfering signals

Sam Ben-Yaakov, H. Guterman

Department of Electrical & Computer Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A model for error response in differential pulse anodic stripping voltammetry in the presence of a deterministic signal is proposed and successfully applied to predict the error in a practical instrumentation system. It is demonstrated that the system is efficient in rejecting 50 Hz and its harmonics, but produces a relatively large error for interfering signals of low frequencies. The sensitivity of the method in the determination of Cd(II) is estimated theoretically and verified experimentally for the polarograph studied.

Original language	English
Pages (from-to)	41-51
Number of pages	11
Journal	Journal of Electroanalytical Chemistry
Volume	125
Issue number	1
DOIs	https://doi.org/10.1016/S0022-0728(81)80322-1
State	Published - 10 Aug 1981

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/S0022-0728(81)80322-1

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title = "Sensitivity of an integrating differential pulse polarograph to interfering signals",

abstract = "A model for error response in differential pulse anodic stripping voltammetry in the presence of a deterministic signal is proposed and successfully applied to predict the error in a practical instrumentation system. It is demonstrated that the system is efficient in rejecting 50 Hz and its harmonics, but produces a relatively large error for interfering signals of low frequencies. The sensitivity of the method in the determination of Cd(II) is estimated theoretically and verified experimentally for the polarograph studied.",

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AU - Ben-Yaakov, Sam

AU - Guterman, H.

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N2 - A model for error response in differential pulse anodic stripping voltammetry in the presence of a deterministic signal is proposed and successfully applied to predict the error in a practical instrumentation system. It is demonstrated that the system is efficient in rejecting 50 Hz and its harmonics, but produces a relatively large error for interfering signals of low frequencies. The sensitivity of the method in the determination of Cd(II) is estimated theoretically and verified experimentally for the polarograph studied.

AB - A model for error response in differential pulse anodic stripping voltammetry in the presence of a deterministic signal is proposed and successfully applied to predict the error in a practical instrumentation system. It is demonstrated that the system is efficient in rejecting 50 Hz and its harmonics, but produces a relatively large error for interfering signals of low frequencies. The sensitivity of the method in the determination of Cd(II) is estimated theoretically and verified experimentally for the polarograph studied.

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DO - 10.1016/S0022-0728(81)80322-1

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JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

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ER -

Sensitivity of an integrating differential pulse polarograph to interfering signals

Abstract

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