Sesquiacetylenes

J. Y. Becker; A. Y. Meyer; J. Klein

doi:10.1007/BF00532187

Sesquiacetylenes

J. Y. Becker, A. Y. Meyer, J. Klein

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

All-valence-electron SCF calculations support the linear "sesquiacetylenic" geometry in propargylic dianions. The two accompanying univalent cations are close to the central carbon, with an angle MC²M of 90°. The migration of lithium in allylic systems is interpreted as an intramolecular sigmatropic rearrangement.

Original language	English
Pages (from-to)	313-317
Number of pages	5
Journal	Theoretica Chimica Acta
Volume	29
Issue number	4
DOIs	https://doi.org/10.1007/BF00532187
State	Published - 1 Dec 1973
Externally published	Yes

ASJC Scopus subject areas

Chiropractic

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10.1007/BF00532187

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title = "Sesquiacetylenes",

abstract = "All-valence-electron SCF calculations support the linear {"}sesquiacetylenic{"} geometry in propargylic dianions. The two accompanying univalent cations are close to the central carbon, with an angle MC2M of 90°. The migration of lithium in allylic systems is interpreted as an intramolecular sigmatropic rearrangement.",

author = "Becker, {J. Y.} and Meyer, {A. Y.} and J. Klein",

year = "1973",

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doi = "10.1007/BF00532187",

language = "English",

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journal = "Theoretica Chimica Acta",

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TY - JOUR

T1 - Sesquiacetylenes

AU - Becker, J. Y.

AU - Meyer, A. Y.

AU - Klein, J.

PY - 1973/12/1

Y1 - 1973/12/1

N2 - All-valence-electron SCF calculations support the linear "sesquiacetylenic" geometry in propargylic dianions. The two accompanying univalent cations are close to the central carbon, with an angle MC2M of 90°. The migration of lithium in allylic systems is interpreted as an intramolecular sigmatropic rearrangement.

AB - All-valence-electron SCF calculations support the linear "sesquiacetylenic" geometry in propargylic dianions. The two accompanying univalent cations are close to the central carbon, with an angle MC2M of 90°. The migration of lithium in allylic systems is interpreted as an intramolecular sigmatropic rearrangement.

UR - http://www.scopus.com/inward/record.url?scp=34250443669&partnerID=8YFLogxK

U2 - 10.1007/BF00532187

DO - 10.1007/BF00532187

M3 - Article

AN - SCOPUS:34250443669

SN - 0040-5744

VL - 29

SP - 313

EP - 317

JO - Theoretica Chimica Acta

JF - Theoretica Chimica Acta

IS - 4

ER -

Sesquiacetylenes

Abstract

ASJC Scopus subject areas

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