Sesquiacetylenic and allenic structures of prop-2-ynyl dianions

Josef Klein, James Y. Becker

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Addition of hexamethylphosphoric triamide to solutions of prop-2-ynyl dilithio-derivatives causes the disappearance of their strong i.r. absorption bands at 1800-1900 cm-1 and the appearance of a medium new band at ca. 2050 cm-1, indicating that a structure trans-formation from an allenic to a sesquiacetylenic form has taken place.

Original languageEnglish
Pages (from-to)576-577
Number of pages2
JournalChemical Communications
Issue number16
DOIs
StatePublished - 1 Jan 1973
Externally publishedYes

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