Shielding anisotropy of H-bonded protons in Cs2GeF6·4HF

N. K. Moroz, A. M. Panich, S. P. Gabuda

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The chemical shift anisotropy of H-bonded protons in polycrystalline Cs2GeF6·4HF was determined by the analysis of NMR continuous wave spectra narrowed by the HF molecular diffusion in the crystal lattice. High resolution of spectral components was achieved due to "selective averaging" of the intermolecular dipole interaction. The derived value of ΔσH = 39 ± 7 ppm is close to that for bifluoride ion in KHF2. For 19F ΔσF = 86 ± 4 ppm was determined.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalJournal of Magnetic Resonance (1969)
Volume53
Issue number1
DOIs
StatePublished - 1 Jun 1983
Externally publishedYes

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