Silica Support Affects the Catalytic Hydrogen Evolution by Silver

Gifty Sara Rolly, Alina Sermiagin, Dan Meyerstein, Tomer Zidki

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Silica supported silver nanoparticles, SiO2-Ag0-NPs, catalyze the hydrolysis of BH4. A comparison of the isotopic composition of the hydrogen formed in the hydrolysis of BD4 points out that the contribution of hydrides, the Heyrovsky mechanism, rather than that of hydrogen atoms, the Tafel mechanism, to the hydrogen evolution is considerably larger for the SiO2-Ag0-NPs catalyzed process than for the Ag0-NPs catalyzed process. This indicates some electron transfer from the SiO2 to the silver that increases the negative charge on the Ag0-NPs.

Original languageEnglish
Pages (from-to)3054-3058
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2021
Issue number30
DOIs
StatePublished - 13 Aug 2021

Keywords

  • HER
  • Heyrovsky mechanism
  • Isotopic hydrogen composition
  • Kinetics
  • NaBD
  • Silica support
  • Silver nanoparticles

ASJC Scopus subject areas

  • Inorganic Chemistry

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