Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone

I. D. Kalikhman; O. B. Bannikova; L. I. Belousova; O. A. Kruglaya; N. S. Vyazankin

doi:10.1007/BF00952221

Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone

I. D. Kalikhman, O. B. Bannikova, L. I. Belousova, O. A. Kruglaya, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Using the dynamic PMR method, it was shown that the silylotropic rearrangements in the trialkylsilyl derivatives of acetoacetic ester, malonic esters, and benzoylacetone have an intramolecular character, while the substituents, framing the β-dicarbonyl fragment, affect the thermodynamic and kinetic parameters of the process.

Original language	English
Pages (from-to)	1570-1572
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	30
Issue number	8
DOIs	https://doi.org/10.1007/BF00952221
State	Published - 1 Aug 1981
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF00952221

Cite this

@article{2a6e3f2eb6de49b5bfb1eda41661f08c,

title = "Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone",

abstract = "Using the dynamic PMR method, it was shown that the silylotropic rearrangements in the trialkylsilyl derivatives of acetoacetic ester, malonic esters, and benzoylacetone have an intramolecular character, while the substituents, framing the β-dicarbonyl fragment, affect the thermodynamic and kinetic parameters of the process.",

author = "Kalikhman, {I. D.} and Bannikova, {O. B.} and Belousova, {L. I.} and Kruglaya, {O. A.} and Vyazankin, {N. S.}",

year = "1981",

month = aug,

day = "1",

doi = "10.1007/BF00952221",

language = "English",

volume = "30",

pages = "1570--1572",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "8",

}

Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone. / Kalikhman, I. D.; Bannikova, O. B.; Belousova, L. I. et al.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 30, No. 8, 01.08.1981, p. 1570-1572.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone

AU - Kalikhman, I. D.

AU - Bannikova, O. B.

AU - Belousova, L. I.

AU - Kruglaya, O. A.

AU - Vyazankin, N. S.

PY - 1981/8/1

Y1 - 1981/8/1

N2 - Using the dynamic PMR method, it was shown that the silylotropic rearrangements in the trialkylsilyl derivatives of acetoacetic ester, malonic esters, and benzoylacetone have an intramolecular character, while the substituents, framing the β-dicarbonyl fragment, affect the thermodynamic and kinetic parameters of the process.

AB - Using the dynamic PMR method, it was shown that the silylotropic rearrangements in the trialkylsilyl derivatives of acetoacetic ester, malonic esters, and benzoylacetone have an intramolecular character, while the substituents, framing the β-dicarbonyl fragment, affect the thermodynamic and kinetic parameters of the process.

UR - http://www.scopus.com/inward/record.url?scp=34250230018&partnerID=8YFLogxK

U2 - 10.1007/BF00952221

DO - 10.1007/BF00952221

M3 - Article

AN - SCOPUS:34250230018

SN - 0568-5230

VL - 30

SP - 1570

EP - 1572

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 8

ER -

Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this