Silylotropy and the29Si NMR spectrum of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one

I. D. Kalikhman; O. B. Bannikova; L. I. Belousova; O. A. Vyazankina; N. S. Vyazankin

doi:10.1007/BF00956621

Silylotropy and the²⁹Si NMR spectrum of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one

I. D. Kalikhman, O. B. Bannikova, L. I. Belousova, O. A. Vyazankina, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

Abstract

¹H,¹³C, and²⁹Si NMR spectroscopy was used to study the structure and silylotropy of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one. The temperature dependence of the²⁹Si NMR chemical shifts indicated the existence of an intermediate with pentacoordinated silicon.

Original language	English
Pages (from-to)	1293-1295
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	35
Issue number	6
DOIs	https://doi.org/10.1007/BF00956621
State	Published - 1 Jun 1986
Externally published	Yes

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General Chemistry

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title = "Silylotropy and the29Si NMR spectrum of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one",

abstract = "1H,13C, and29Si NMR spectroscopy was used to study the structure and silylotropy of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one. The temperature dependence of the29Si NMR chemical shifts indicated the existence of an intermediate with pentacoordinated silicon.",

author = "Kalikhman, {I. D.} and Bannikova, {O. B.} and Belousova, {L. I.} and Vyazankina, {O. A.} and Vyazankin, {N. S.}",

year = "1986",

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language = "English",

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AU - Kalikhman, I. D.

AU - Bannikova, O. B.

AU - Belousova, L. I.

AU - Vyazankina, O. A.

AU - Vyazankin, N. S.

PY - 1986/6/1

Y1 - 1986/6/1

N2 - 1H,13C, and29Si NMR spectroscopy was used to study the structure and silylotropy of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one. The temperature dependence of the29Si NMR chemical shifts indicated the existence of an intermediate with pentacoordinated silicon.

AB - 1H,13C, and29Si NMR spectroscopy was used to study the structure and silylotropy of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one. The temperature dependence of the29Si NMR chemical shifts indicated the existence of an intermediate with pentacoordinated silicon.

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SN - 0568-5230

VL - 35

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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Silylotropy and the²⁹Si NMR spectrum of 2-[dimethyl(pentafluorophenyl)siloxy]-2-penten-4-one

Abstract

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