@article{69481cd719214be1a798fabc93034074,
title = "Single-Ion Magnet Et4N[CoII(hfac)3] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling",
abstract = "In this article we report the synthesis and structure of the new Co(II) complex Et4N[CoII(hfac)3] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis of the magnetic characteristics based on the complementary experimental techniques such as static and dynamic magnetic measurements, electron paramagnetic resonance spectroscopy in conjunction with the theoretical modeling (parametric Hamiltonian and ab initio calculations) demonstrates that the SIM properties of I arise from the nonuniaxial magnetic anisotropy with strong positive axial and significant rhombic contributions.",
author = "Palii, {Andrew V.} and Korchagin, {Denis V.} and Yureva, {Elena A.} and Akimov, {Alexander V.} and Misochko, {Eugenii Ya} and Shilov, {Gennady V.} and Talantsev, {Artem D.} and Morgunov, {Roman B.} and Aldoshin, {Sergey M.} and Tsukerblat, {Boris S.}",
note = "Funding Information: The authors thank the research team of the laboratory for microanalysis at the A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences. This work was supported by the Russian Foundation for Basic Research (Grant No. 16-33-00464 mol-a) and the Presidium of the Russian Academy of Sciences (Program No. 35). Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2016",
month = oct,
day = "3",
doi = "10.1021/acs.inorgchem.6b01473",
language = "English",
volume = "55",
pages = "9696--9706",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "19",
}