Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands

Christian Schäffer; Ana Maria Todea; Hartmut Bögge; Emmanuel Cadot; Pierre Gouzerh; Sivil Kopilevich; Ira A. Weinstock; Achim Müller

doi:10.1002/anie.201104642

Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands

Christian Schäffer, Ana Maria Todea, Hartmut Bögge, Emmanuel Cadot, Pierre Gouzerh, Sivil Kopilevich, Ira A. Weinstock, Achim Müller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

A hard capsule gets soft: The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well-known porous metal-oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.

Original language	English
Pages (from-to)	12326-12329
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	51
DOIs	https://doi.org/10.1002/anie.201104642
State	Published - 16 Dec 2011

Keywords

molybdenum
polyoxometalates
porous materials
sulfur
tungsten

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201104642

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title = "Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands",

abstract = "A hard capsule gets soft: The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well-known porous metal-oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.",

keywords = "molybdenum, polyoxometalates, porous materials, sulfur, tungsten",

author = "Christian Sch{\"a}ffer and Todea, {Ana Maria} and Hartmut B{\"o}gge and Emmanuel Cadot and Pierre Gouzerh and Sivil Kopilevich and Weinstock, {Ira A.} and Achim M{\"u}ller",

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T2 - Substituting 60 oxide by 60 sulfide ligands

AU - Schäffer, Christian

AU - Todea, Ana Maria

AU - Bögge, Hartmut

AU - Cadot, Emmanuel

AU - Gouzerh, Pierre

AU - Kopilevich, Sivil

AU - Weinstock, Ira A.

AU - Müller, Achim

PY - 2011/12/16

Y1 - 2011/12/16

N2 - A hard capsule gets soft: The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well-known porous metal-oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.

AB - A hard capsule gets soft: The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well-known porous metal-oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.

KW - molybdenum

KW - polyoxometalates

KW - porous materials

KW - sulfur

KW - tungsten

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M3 - Article

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ER -

Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands

Abstract

Keywords

ASJC Scopus subject areas

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