Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands

Christian Schäffer, Ana Maria Todea, Hartmut Bögge, Emmanuel Cadot, Pierre Gouzerh, Sivil Kopilevich, Ira A. Weinstock, Achim Müller

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

A hard capsule gets soft: The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well-known porous metal-oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.

Original languageEnglish
Pages (from-to)12326-12329
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number51
DOIs
StatePublished - 16 Dec 2011

Keywords

  • molybdenum
  • polyoxometalates
  • porous materials
  • sulfur
  • tungsten

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

Fingerprint

Dive into the research topics of 'Softening of pore and interior properties of a metal-oxide-based capsule: Substituting 60 oxide by 60 sulfide ligands'. Together they form a unique fingerprint.

Cite this