Solvent mediated synthesis of homoleptic tri and tetranuclear nickel complex derived from [Ni₂(µ-SeC₅H₄N)₂(dppe)₂]²⁺ and theoretical studies

Keyphrases

• Solvent-mediated 100%
• Mediated Synthesis 100%
• Dppe 100%
• Homoleptic 100%
• Tetranuclear Nickel Complex 100%
• Ni(II) 60%
• Methanol 40%
• Electronic Structure 40%
• Formate 40%
• Phenylacetate 40%
• Broken-symmetry Theory 40%
• X-ray 20%
• Elemental Analysis 20%
• Molecular Structure 20%
• Complex Structure 20%
• X-ray Diffraction (XRD) Analysis 20%
• Geometry Optimization 20%
• Chlorinated Solvents 20%
• 1H NMR Spectroscopy 20%
• Magnetic Exchange Interaction 20%
• Density Functional Calculations 20%
• Thermal Studies 20%
• Spin Density 20%
• Dichloromethane 20%
• Antiferromagnetic Interaction 20%
• Ferromagnetic Interaction 20%
• Molecular Orbital 20%
• Trinuclear Complex 20%
• J Value 20%
• Electronic Nature 20%
• Binuclear Complexes 20%
• Density Analysis 20%
• Cubane Core 20%

Chemistry

• Density Functional Theory 100%
• Formate 100%
• Methanol 100%
• Electronic State 100%
• Phenylacetate 100%
• Phase Composition 50%
• Ground State 50%
• Antiferromagnetic 50%
• Molecular Structure 50%
• X-Ray Diffraction 50%
• Exchange Interaction 50%
• Dichloromethane 50%
• Single Crystal X-Ray Diffraction 50%
• Molecular Orbital 50%
• Elemental Analysis 50%
• 31P{1H}-NMR Spectroscopy 50%
• Cubane 50%