Some properties of 2-alkoxy-1-alken-3-ols

N. A. Keiko; T. N. Musorina; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00949224

Some properties of 2-alkoxy-1-alken-3-ols

N. A. Keiko, T. N. Musorina, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of 2-alkoxyacroleins with Grignard reagent gave some new 2-alkoxy-1-alken-3-ols, which in the presence of p-toluenesulfonic acid are cyclodimerized to 2,3,5,6-tetraalkyl-2,5-dialkoxy-1,4-dioxanes, which tend to cleave ethanol to give 2,3,5,6-tetraalkyl-5-alkoxy-1,4-dioxenes.

Original language	English
Pages (from-to)	1793-1796
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	29
Issue number	11
DOIs	https://doi.org/10.1007/BF00949224
State	Published - 1 Nov 1980
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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abstract = "The reaction of 2-alkoxyacroleins with Grignard reagent gave some new 2-alkoxy-1-alken-3-ols, which in the presence of p-toluenesulfonic acid are cyclodimerized to 2,3,5,6-tetraalkyl-2,5-dialkoxy-1,4-dioxanes, which tend to cleave ethanol to give 2,3,5,6-tetraalkyl-5-alkoxy-1,4-dioxenes.",

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AU - Kalikhman, I. D.

AU - Voronkov, M. G.

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N2 - The reaction of 2-alkoxyacroleins with Grignard reagent gave some new 2-alkoxy-1-alken-3-ols, which in the presence of p-toluenesulfonic acid are cyclodimerized to 2,3,5,6-tetraalkyl-2,5-dialkoxy-1,4-dioxanes, which tend to cleave ethanol to give 2,3,5,6-tetraalkyl-5-alkoxy-1,4-dioxenes.

AB - The reaction of 2-alkoxyacroleins with Grignard reagent gave some new 2-alkoxy-1-alken-3-ols, which in the presence of p-toluenesulfonic acid are cyclodimerized to 2,3,5,6-tetraalkyl-2,5-dialkoxy-1,4-dioxanes, which tend to cleave ethanol to give 2,3,5,6-tetraalkyl-5-alkoxy-1,4-dioxenes.

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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IS - 11

ER -

Some properties of 2-alkoxy-1-alken-3-ols

Abstract

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