Spectroscopy of multisites Cr3+ and Nd3+ in yttrium aluminum perovskite

J. A. Mares, G. Boulon, A. Brenier, L. Lou, S. R. Rotman

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Selectively excited Cr3+ and Nd3+ emission spectra and excitation spectra of YAlO3:Nd, Cr crystals are presented. Up to eight Nd3+ and three Cr3+ multisites are observed in these crystals. Cr3+→Nd3+ energy transfer is observed between various multisites starting from 2E Cr3+ energy levels. Cr3+ donor decay can be adequately fitted according to the standard Inokuti-Hirayama theory but a spatial correlation between Cr3+ donors and Nd3+ acceptors results in a better fit of Cr3+ fluorescence decay curves.

Original languageEnglish
Pages (from-to)105-111
Number of pages7
JournalChemical Physics Letters
Volume217
Issue number1-2
DOIs
StatePublished - 7 Jan 1994

ASJC Scopus subject areas

  • Physics and Astronomy (all)
  • Physical and Theoretical Chemistry

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