An experimental comparison is made with theoretical linewidth, lineshape, and slopes under conditions of saturation without using a Gaussian lineshape approximation. Satisfactory agreement is obtained and it is shown how the modulation can cause the line to rebroaden with increasing rf field intensity. It is shown that T1Z/T1D = 2.0 for titanium hydride, as expected for relaxation by conduction electrons.
|Number of pages||6|
|Journal||Journal of Magnetic Resonance (1969)|
|State||Published - 1 Jan 1977|