Stannylene complexes of manganese, iron, and platinum

S. S. Shapovalov; A. A. Pasynskii; Yu V. Torubaev; I. V. Skabitskii; M. Scheer; M. Bodensteiner

doi:10.1134/S1070328414030087

Stannylene complexes of manganese, iron, and platinum

S. S. Shapovalov, A. A. Pasynskii, Yu V. Torubaev, I. V. Skabitskii, M. Scheer, M. Bodensteiner

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A number of stannylene complexes with different M: Sn ratios were obtained using various metals and substituents at the tin atom. The structures of the complexes were examined. A reaction of CpMn(CO)₂THF with (Ph ₄As)⁺(SnCl₃)^- gave the ionic complex [Ph₄As]⁺[CpMn(CO)₂SnCl₃] ^- (I). The action of C₆F₅MgBr on the complex C₅H₅Mn(CO)(NO)SnCl₃ produced C ₅H₅Mn(CO)(NO)Sn(C₆F₅)₃ (II). Replacement of the Cl ions in the complex [CpFe(CO)₂] ₂SnCl₂ by phenylacetylenide groups gave rise to the neutral complex [CpFe(CO)₂]₂Sn(C≡CPh)₂ (III). A reaction of (Dppm)PtCl₂ (Dppm is 1,1-bis(diphenylphosphino) methane) with SnCl₂ · 2H₂O in the presence of diglyme yielded the ionic complex [η³-CH₃O(CH ₂)₂O(CH₂)₂OCH₃)SnCl] ⁺[(η ²-Dppm)Pt(SnCl₃)₃] ^- (IV). Transmetalation in a reaction of [(Dppe)₂CoCl] [SnCl₃] · PhBr (Dppe is 1,2-bis(diphenylphosphino)ethane) with (Dcpd)PtCl₂ (Dcpd is dicyclopentadiene) in the presence of SnCl ₂ afforded the ionic complex [Pt(Dppe)₂] ₃[Pt(SnCl₃)₅]₂ (V). Structures I-V were identified by X-ray diffraction. In these structures, the formally single bonds between the atoms of transition metals M (Mn, Fe, and Pt) and Main Group heavy elements (Sn and P) having vacant d orbitals are appreciably shortened. The M-Sn bond length in complexes II and III are virtually independent of the substituents at the tin atom and the Pt-Sn bond length in complexes IV and V is virtually independent of the Pt: Sn ratio.

Original language	English
Pages (from-to)	131-137
Number of pages	7
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	40
Issue number	3
DOIs	https://doi.org/10.1134/S1070328414030087
State	Published - 1 Jan 2014
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1134/S1070328414030087

Cite this

@article{3886f71e6ac4498f82bab775d5aabfec,

title = "Stannylene complexes of manganese, iron, and platinum",

abstract = "A number of stannylene complexes with different M: Sn ratios were obtained using various metals and substituents at the tin atom. The structures of the complexes were examined. A reaction of CpMn(CO)2THF with (Ph 4As)+(SnCl3)- gave the ionic complex [Ph4As]+[CpMn(CO)2SnCl3] - (I). The action of C6F5MgBr on the complex C5H5Mn(CO)(NO)SnCl3 produced C 5H5Mn(CO)(NO)Sn(C6F5)3 (II). Replacement of the Cl ions in the complex [CpFe(CO)2] 2SnCl2 by phenylacetylenide groups gave rise to the neutral complex [CpFe(CO)2]2Sn(C≡CPh)2 (III). A reaction of (Dppm)PtCl2 (Dppm is 1,1-bis(diphenylphosphino) methane) with SnCl2 · 2H2O in the presence of diglyme yielded the ionic complex [η3-CH3O(CH 2)2O(CH2)2OCH3)SnCl] +[(η 2-Dppm)Pt(SnCl3)3] - (IV). Transmetalation in a reaction of [(Dppe)2CoCl] [SnCl3] · PhBr (Dppe is 1,2-bis(diphenylphosphino)ethane) with (Dcpd)PtCl2 (Dcpd is dicyclopentadiene) in the presence of SnCl 2 afforded the ionic complex [Pt(Dppe)2] 3[Pt(SnCl3)5]2 (V). Structures I-V were identified by X-ray diffraction. In these structures, the formally single bonds between the atoms of transition metals M (Mn, Fe, and Pt) and Main Group heavy elements (Sn and P) having vacant d orbitals are appreciably shortened. The M-Sn bond length in complexes II and III are virtually independent of the substituents at the tin atom and the Pt-Sn bond length in complexes IV and V is virtually independent of the Pt: Sn ratio.",

author = "Shapovalov, {S. S.} and Pasynskii, {A. A.} and Torubaev, {Yu V.} and Skabitskii, {I. V.} and M. Scheer and M. Bodensteiner",

note = "Funding Information: This work was supported by the Russian Founda tion for Basic Research (projects nos. 12 03 00860, 12 03 33101, and 13 03 92691), the Presidium of the Russian Academy of Sciences (grant no. 8P23), the Division of Chemistry and Materials Sciences of the Russian Academy of Sciences (grant no. OKh 1.3), the Council on Grants at the President of the Russian Federation (grant no. MK 7179.2012.3), the State Support Program for Leading Scientific Schools (NSh 1670.2012.3), and the Ministry of Education tact (3.356 {\AA}) with one of the SnCl3 groups in the anion (angle ClSnO, 135.82°). Note that the presence of the tin atom in the cation leads to a total Pt : Sn ratio of 1 : 4 in complex IV.",

year = "2014",

month = jan,

day = "1",

doi = "10.1134/S1070328414030087",

language = "English",

volume = "40",

pages = "131--137",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "3",

}

TY - JOUR

T1 - Stannylene complexes of manganese, iron, and platinum

AU - Shapovalov, S. S.

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Skabitskii, I. V.

AU - Scheer, M.

AU - Bodensteiner, M.

N1 - Funding Information: This work was supported by the Russian Founda tion for Basic Research (projects nos. 12 03 00860, 12 03 33101, and 13 03 92691), the Presidium of the Russian Academy of Sciences (grant no. 8P23), the Division of Chemistry and Materials Sciences of the Russian Academy of Sciences (grant no. OKh 1.3), the Council on Grants at the President of the Russian Federation (grant no. MK 7179.2012.3), the State Support Program for Leading Scientific Schools (NSh 1670.2012.3), and the Ministry of Education tact (3.356 Å) with one of the SnCl3 groups in the anion (angle ClSnO, 135.82°). Note that the presence of the tin atom in the cation leads to a total Pt : Sn ratio of 1 : 4 in complex IV.

PY - 2014/1/1

Y1 - 2014/1/1

N2 - A number of stannylene complexes with different M: Sn ratios were obtained using various metals and substituents at the tin atom. The structures of the complexes were examined. A reaction of CpMn(CO)2THF with (Ph 4As)+(SnCl3)- gave the ionic complex [Ph4As]+[CpMn(CO)2SnCl3] - (I). The action of C6F5MgBr on the complex C5H5Mn(CO)(NO)SnCl3 produced C 5H5Mn(CO)(NO)Sn(C6F5)3 (II). Replacement of the Cl ions in the complex [CpFe(CO)2] 2SnCl2 by phenylacetylenide groups gave rise to the neutral complex [CpFe(CO)2]2Sn(C≡CPh)2 (III). A reaction of (Dppm)PtCl2 (Dppm is 1,1-bis(diphenylphosphino) methane) with SnCl2 · 2H2O in the presence of diglyme yielded the ionic complex [η3-CH3O(CH 2)2O(CH2)2OCH3)SnCl] +[(η 2-Dppm)Pt(SnCl3)3] - (IV). Transmetalation in a reaction of [(Dppe)2CoCl] [SnCl3] · PhBr (Dppe is 1,2-bis(diphenylphosphino)ethane) with (Dcpd)PtCl2 (Dcpd is dicyclopentadiene) in the presence of SnCl 2 afforded the ionic complex [Pt(Dppe)2] 3[Pt(SnCl3)5]2 (V). Structures I-V were identified by X-ray diffraction. In these structures, the formally single bonds between the atoms of transition metals M (Mn, Fe, and Pt) and Main Group heavy elements (Sn and P) having vacant d orbitals are appreciably shortened. The M-Sn bond length in complexes II and III are virtually independent of the substituents at the tin atom and the Pt-Sn bond length in complexes IV and V is virtually independent of the Pt: Sn ratio.

AB - A number of stannylene complexes with different M: Sn ratios were obtained using various metals and substituents at the tin atom. The structures of the complexes were examined. A reaction of CpMn(CO)2THF with (Ph 4As)+(SnCl3)- gave the ionic complex [Ph4As]+[CpMn(CO)2SnCl3] - (I). The action of C6F5MgBr on the complex C5H5Mn(CO)(NO)SnCl3 produced C 5H5Mn(CO)(NO)Sn(C6F5)3 (II). Replacement of the Cl ions in the complex [CpFe(CO)2] 2SnCl2 by phenylacetylenide groups gave rise to the neutral complex [CpFe(CO)2]2Sn(C≡CPh)2 (III). A reaction of (Dppm)PtCl2 (Dppm is 1,1-bis(diphenylphosphino) methane) with SnCl2 · 2H2O in the presence of diglyme yielded the ionic complex [η3-CH3O(CH 2)2O(CH2)2OCH3)SnCl] +[(η 2-Dppm)Pt(SnCl3)3] - (IV). Transmetalation in a reaction of [(Dppe)2CoCl] [SnCl3] · PhBr (Dppe is 1,2-bis(diphenylphosphino)ethane) with (Dcpd)PtCl2 (Dcpd is dicyclopentadiene) in the presence of SnCl 2 afforded the ionic complex [Pt(Dppe)2] 3[Pt(SnCl3)5]2 (V). Structures I-V were identified by X-ray diffraction. In these structures, the formally single bonds between the atoms of transition metals M (Mn, Fe, and Pt) and Main Group heavy elements (Sn and P) having vacant d orbitals are appreciably shortened. The M-Sn bond length in complexes II and III are virtually independent of the substituents at the tin atom and the Pt-Sn bond length in complexes IV and V is virtually independent of the Pt: Sn ratio.

UR - http://www.scopus.com/inward/record.url?scp=84896321252&partnerID=8YFLogxK

U2 - 10.1134/S1070328414030087

DO - 10.1134/S1070328414030087

M3 - Article

AN - SCOPUS:84896321252

SN - 1070-3284

VL - 40

SP - 131

EP - 137

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 3

ER -

Stannylene complexes of manganese, iron, and platinum

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this