Stereochemistry of reaction of diethylamine with diacetylene

A. N. Volkov; A. N. Vavilova; L. V. Sokolyanskaya; M. V. Sigalov

doi:10.1007/BF00949794

Stereochemistry of reaction of diethylamine with diacetylene

A. N. Volkov, A. N. Vavilova, L. V. Sokolyanskaya, M. V. Sigalov

Research output: Contribution to journal › Article › peer-review

Abstract

1. The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature. 2. The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.

Original language	English
Pages (from-to)	613-615
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	31
Issue number	3
DOIs	https://doi.org/10.1007/BF00949794
State	Published - 1 Jan 1982
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF00949794

Cite this

@article{c0b61879427a4562adf2d3095efca0b3,

title = "Stereochemistry of reaction of diethylamine with diacetylene",

abstract = "1. The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature. 2. The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.",

author = "Volkov, {A. N.} and Vavilova, {A. N.} and Sokolyanskaya, {L. V.} and Sigalov, {M. V.}",

year = "1982",

month = jan,

day = "1",

doi = "10.1007/BF00949794",

language = "English",

volume = "31",

pages = "613--615",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Stereochemistry of reaction of diethylamine with diacetylene

AU - Volkov, A. N.

AU - Vavilova, A. N.

AU - Sokolyanskaya, L. V.

AU - Sigalov, M. V.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - 1. The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature. 2. The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.

AB - 1. The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature. 2. The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.

UR - http://www.scopus.com/inward/record.url?scp=34250227837&partnerID=8YFLogxK

U2 - 10.1007/BF00949794

DO - 10.1007/BF00949794

M3 - Article

AN - SCOPUS:34250227837

SN - 0568-5230

VL - 31

SP - 613

EP - 615

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 3

ER -

Stereochemistry of reaction of diethylamine with diacetylene

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this