Stereochemistry of reaction of diethylamine with diacetylene

A. N. Volkov, A. N. Vavilova, L. V. Sokolyanskaya, M. V. Sigalov

Research output: Contribution to journalArticlepeer-review

Abstract

1. The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature. 2. The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.

Original languageEnglish
Pages (from-to)613-615
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume31
Issue number3
DOIs
StatePublished - 1 Mar 1982
Externally publishedYes

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