Stereoelegtronic effects in phosphonates

M. V. Sigalov, V. A. Pestunovich, V. M. Nikitin, A. S. Atavin, M. Ya Khil'ko

Research output: Contribution to journalArticlepeer-review


1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.

Original languageEnglish
Pages (from-to)1086-1087
Number of pages2
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Issue number5
StatePublished - 1 May 1977
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)


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