Stereoelegtronic effects in phosphonates

M. V. Sigalov; V. A. Pestunovich; V. M. Nikitin; A. S. Atavin; M. Ya Khil'ko

doi:10.1007/BF01152728

Stereoelegtronic effects in phosphonates

M. V. Sigalov, V. A. Pestunovich, V. M. Nikitin, A. S. Atavin, M. Ya Khil'ko

Research output: Contribution to journal › Article › peer-review

Abstract

1. A study was made of the³¹P chemical shifts and the¹J_31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached³¹P and¹³C nuclei was elucidated.

Original language	English
Pages (from-to)	1086-1087
Number of pages	2
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	5
DOIs	https://doi.org/10.1007/BF01152728
State	Published - 1 Jan 1977
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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@article{d6b8790573ba4d5997b3d6509cb24938,

title = "Stereoelegtronic effects in phosphonates",

abstract = "1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.",

author = "Sigalov, {M. V.} and Pestunovich, {V. A.} and Nikitin, {V. M.} and Atavin, {A. S.} and Khil'ko, {M. Ya}",

note = "Funding Information: The present study was supported by the Science and Technology Department of Zhejiang Province (grant no. 2014C37027 and 2014C37067) and the National Natural Science Foundation of China (grant no. 81371953).",

year = "1977",

month = jan,

day = "1",

doi = "10.1007/BF01152728",

language = "English",

volume = "26",

pages = "1086--1087",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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publisher = "Springer New York",

number = "5",

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TY - JOUR

T1 - Stereoelegtronic effects in phosphonates

AU - Sigalov, M. V.

AU - Pestunovich, V. A.

AU - Nikitin, V. M.

AU - Atavin, A. S.

AU - Khil'ko, M. Ya

N1 - Funding Information: The present study was supported by the Science and Technology Department of Zhejiang Province (grant no. 2014C37027 and 2014C37067) and the National Natural Science Foundation of China (grant no. 81371953).

PY - 1977/1/1

Y1 - 1977/1/1

N2 - 1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.

AB - 1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.

UR - http://www.scopus.com/inward/record.url?scp=34250298544&partnerID=8YFLogxK

U2 - 10.1007/BF01152728

DO - 10.1007/BF01152728

M3 - Article

AN - SCOPUS:34250298544

SN - 0568-5230

VL - 26

SP - 1086

EP - 1087

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 5

ER -

Stereoelegtronic effects in phosphonates

Abstract

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