Stereoelegtronic effects in phosphonates

M. V. Sigalov; V. A. Pestunovich; V. M. Nikitin; A. S. Atavin; M. Ya Khil'ko

doi:10.1007/BF01152728

Stereoelegtronic effects in phosphonates

M. V. Sigalov
, V. A. Pestunovich
, V. M. Nikitin
, A. S. Atavin
, M. Ya Khil'ko

Research output: Contribution to journal › Article › peer-review

Abstract

1. A study was made of the³¹P chemical shifts and the¹J_31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached³¹P and¹³C nuclei was elucidated.

Original language	English
Pages (from-to)	1086-1087
Number of pages	2
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	5
DOIs	https://doi.org/10.1007/BF01152728
State	Published - 1 Jan 1977
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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AU - Sigalov, M. V.

AU - Pestunovich, V. A.

AU - Nikitin, V. M.

AU - Atavin, A. S.

AU - Khil'ko, M. Ya

PY - 1977/1/1

Y1 - 1977/1/1

N2 - 1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.

AB - 1. A study was made of the31P chemical shifts and the1J31P-13C SSCC in a number of phosphonates that contain the same structural fragments in a variable position. 2. The effect of the stereoelectronic effects, interpreted as the p,σ conjugation of the unshared pairs of the oxygen atoms and the P-C bonds, on the SSCC values of the directly attached31P and13C nuclei was elucidated.

UR - https://www.scopus.com/pages/publications/34250298544

U2 - 10.1007/BF01152728

DO - 10.1007/BF01152728

M3 - Article

AN - SCOPUS:34250298544

SN - 0568-5230

VL - 26

SP - 1086

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 5

ER -

Stereoelegtronic effects in phosphonates

Abstract

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