Strong coupling in the optical spectra of polymorphs of a squarylium dye

M. Tristani-Kendra; C. J. Eckhardt; J. Bernstein; E. Goldstein

doi:10.1016/0009-2614(83)80202-4

Strong coupling in the optical spectra of polymorphs of a squarylium dye

M. Tristani-Kendra, C. J. Eckhardt, J. Bernstein, E. Goldstein

Department of Chemistry

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31 Scopus citations

Abstract

The X-ray structure and single-crystal spectra of monoclinic and triclinic dimorphs of a squarylium dye are reported. Crystal polymorphism is shown to be an effective approach for studying excitation energy transfer in crystals. The long-axis-polarized transition leads to quasi-metallic reflection bands which cannot be fitted by molecular polariton calculations in the point-dipole approximation.

Original language	English
Pages (from-to)	57-61
Number of pages	5
Journal	Chemical Physics Letters
Volume	98
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(83)80202-4
State	Published - 10 Jun 1983

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(83)80202-4

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title = "Strong coupling in the optical spectra of polymorphs of a squarylium dye",

abstract = "The X-ray structure and single-crystal spectra of monoclinic and triclinic dimorphs of a squarylium dye are reported. Crystal polymorphism is shown to be an effective approach for studying excitation energy transfer in crystals. The long-axis-polarized transition leads to quasi-metallic reflection bands which cannot be fitted by molecular polariton calculations in the point-dipole approximation.",

author = "M. Tristani-Kendra and Eckhardt, {C. J.} and J. Bernstein and E. Goldstein",

note = "Funding Information: in part by NSF Grant No. DhIR-7908759, ** Work completed in partial fu~~ment of requirements the Ph.D. at the University of Nebraska-Lincoln. Funding Information: * Supported by DOE Grant No. DE-FG-02-79ER10535",

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doi = "10.1016/0009-2614(83)80202-4",

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T1 - Strong coupling in the optical spectra of polymorphs of a squarylium dye

AU - Tristani-Kendra, M.

AU - Eckhardt, C. J.

AU - Bernstein, J.

AU - Goldstein, E.

N1 - Funding Information: in part by NSF Grant No. DhIR-7908759, ** Work completed in partial fu~~ment of requirements the Ph.D. at the University of Nebraska-Lincoln. Funding Information: * Supported by DOE Grant No. DE-FG-02-79ER10535

PY - 1983/6/10

Y1 - 1983/6/10

N2 - The X-ray structure and single-crystal spectra of monoclinic and triclinic dimorphs of a squarylium dye are reported. Crystal polymorphism is shown to be an effective approach for studying excitation energy transfer in crystals. The long-axis-polarized transition leads to quasi-metallic reflection bands which cannot be fitted by molecular polariton calculations in the point-dipole approximation.

AB - The X-ray structure and single-crystal spectra of monoclinic and triclinic dimorphs of a squarylium dye are reported. Crystal polymorphism is shown to be an effective approach for studying excitation energy transfer in crystals. The long-axis-polarized transition leads to quasi-metallic reflection bands which cannot be fitted by molecular polariton calculations in the point-dipole approximation.

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U2 - 10.1016/0009-2614(83)80202-4

DO - 10.1016/0009-2614(83)80202-4

M3 - Article

AN - SCOPUS:0141741083

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SP - 57

EP - 61

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Strong coupling in the optical spectra of polymorphs of a squarylium dye

Abstract

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