Structure and bonding in chlorine-functionalized nanodiamond - nuclear magnetic resonance and x-ray photoelectron spectroscopy study

Alexander M. Panich; Nikolay A. Sergeev; Marcin Olszewski; Natalya Froumin; Arthur T. Dideykin; Vasiliy V. Sokolov; Alexander Ya Vul'

doi:10.1166/jnn.2015.9737

Structure and bonding in chlorine-functionalized nanodiamond - nuclear magnetic resonance and x-ray photoelectron spectroscopy study

Alexander M. Panich, Nikolay A. Sergeev, Marcin Olszewski, Natalya Froumin, Arthur T. Dideykin, Vasiliy V. Sokolov, Alexander Ya Vul'

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

We report on investigation of detonation nanodiamond annealed at 800°C in chlorine atmosphere by means of ¹H, ¹³C and ³⁵Cl nuclear magnetic resonance and X-ray photoelectron spectroscopy. The results of these methods are found to be consistent with each other and evidence formation of chlorine-carbon groups and sp² carbon shell on the nanodiamond surface. The data obtained provide detailed information about the structure and bonding in this diamond nanoparticle. Interaction of nuclear spins with unpaired electron spins of dangling bonds results in fast ¹³C nuclear spin-lattice relaxation.

Original language	English
Pages (from-to)	1030-1036
Number of pages	7
Journal	Journal of Nanoscience and Nanotechnology
Volume	15
Issue number	2
DOIs	https://doi.org/10.1166/jnn.2015.9737
State	Published - 1 Feb 2015

Keywords

Chlorine
Diamond nanoparticles
NMR
XPS

ASJC Scopus subject areas

Bioengineering
General Chemistry
Biomedical Engineering
General Materials Science
Condensed Matter Physics

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title = "Structure and bonding in chlorine-functionalized nanodiamond - nuclear magnetic resonance and x-ray photoelectron spectroscopy study",

abstract = "We report on investigation of detonation nanodiamond annealed at 800°C in chlorine atmosphere by means of 1H, 13C and 35Cl nuclear magnetic resonance and X-ray photoelectron spectroscopy. The results of these methods are found to be consistent with each other and evidence formation of chlorine-carbon groups and sp2 carbon shell on the nanodiamond surface. The data obtained provide detailed information about the structure and bonding in this diamond nanoparticle. Interaction of nuclear spins with unpaired electron spins of dangling bonds results in fast 13C nuclear spin-lattice relaxation.",

keywords = "Chlorine, Diamond nanoparticles, NMR, XPS",

author = "Panich, {Alexander M.} and Sergeev, {Nikolay A.} and Marcin Olszewski and Natalya Froumin and Dideykin, {Arthur T.} and Sokolov, {Vasiliy V.} and Vul', {Alexander Ya}",

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T1 - Structure and bonding in chlorine-functionalized nanodiamond - nuclear magnetic resonance and x-ray photoelectron spectroscopy study

AU - Panich, Alexander M.

AU - Sergeev, Nikolay A.

AU - Olszewski, Marcin

AU - Froumin, Natalya

AU - Dideykin, Arthur T.

AU - Sokolov, Vasiliy V.

AU - Vul', Alexander Ya

PY - 2015/2/1

Y1 - 2015/2/1

N2 - We report on investigation of detonation nanodiamond annealed at 800°C in chlorine atmosphere by means of 1H, 13C and 35Cl nuclear magnetic resonance and X-ray photoelectron spectroscopy. The results of these methods are found to be consistent with each other and evidence formation of chlorine-carbon groups and sp2 carbon shell on the nanodiamond surface. The data obtained provide detailed information about the structure and bonding in this diamond nanoparticle. Interaction of nuclear spins with unpaired electron spins of dangling bonds results in fast 13C nuclear spin-lattice relaxation.

AB - We report on investigation of detonation nanodiamond annealed at 800°C in chlorine atmosphere by means of 1H, 13C and 35Cl nuclear magnetic resonance and X-ray photoelectron spectroscopy. The results of these methods are found to be consistent with each other and evidence formation of chlorine-carbon groups and sp2 carbon shell on the nanodiamond surface. The data obtained provide detailed information about the structure and bonding in this diamond nanoparticle. Interaction of nuclear spins with unpaired electron spins of dangling bonds results in fast 13C nuclear spin-lattice relaxation.

KW - Chlorine

KW - Diamond nanoparticles

KW - NMR

KW - XPS

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AN - SCOPUS:84920703380

SN - 1533-4880

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JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 2

ER -

Structure and bonding in chlorine-functionalized nanodiamond - nuclear magnetic resonance and x-ray photoelectron spectroscopy study

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Keywords

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