Structure of polymers of dimethylbutadiyne

M. G. Chauser; I. D. Kalikhman; M. I. Cherkashin; A. A. Berlin

doi:10.1007/BF00906492

Structure of polymers of dimethylbutadiyne

M. G. Chauser, I. D. Kalikhman, M. I. Cherkashin, A. A. Berlin

Research output: Contribution to journal › Article › peer-review

Abstract

1. The thermal and catalytic polymerization of dimethylbutadiyne leads to polymers that are readily oxidized by atmospheric oxygen. 2. As a result of polymerization, a block copolymer is formed, containing fragments of a substituted polyene and polyacene, together with a small amount of double bonds of the basic chain, isomerized into the side chain. 3. The insolubility of the thermal polymer is apparently due to the formation of a three-dimensional structure during synthesis, while for the catalytic polymer this apparently occurs at the stage of its treatment.

Original language	English
Pages (from-to)	2268-2270
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	18
Issue number	11
DOIs	https://doi.org/10.1007/BF00906492
State	Published - 1 Nov 1969
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF00906492

Cite this

@article{1852dbad2f104b34a4cff42e2d19a6ae,

title = "Structure of polymers of dimethylbutadiyne",

abstract = "1. The thermal and catalytic polymerization of dimethylbutadiyne leads to polymers that are readily oxidized by atmospheric oxygen. 2. As a result of polymerization, a block copolymer is formed, containing fragments of a substituted polyene and polyacene, together with a small amount of double bonds of the basic chain, isomerized into the side chain. 3. The insolubility of the thermal polymer is apparently due to the formation of a three-dimensional structure during synthesis, while for the catalytic polymer this apparently occurs at the stage of its treatment.",

author = "Chauser, {M. G.} and Kalikhman, {I. D.} and Cherkashin, {M. I.} and Berlin, {A. A.}",

year = "1969",

month = nov,

day = "1",

doi = "10.1007/BF00906492",

language = "English",

volume = "18",

pages = "2268--2270",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "11",

}

TY - JOUR

T1 - Structure of polymers of dimethylbutadiyne

AU - Chauser, M. G.

AU - Kalikhman, I. D.

AU - Cherkashin, M. I.

AU - Berlin, A. A.

PY - 1969/11/1

Y1 - 1969/11/1

N2 - 1. The thermal and catalytic polymerization of dimethylbutadiyne leads to polymers that are readily oxidized by atmospheric oxygen. 2. As a result of polymerization, a block copolymer is formed, containing fragments of a substituted polyene and polyacene, together with a small amount of double bonds of the basic chain, isomerized into the side chain. 3. The insolubility of the thermal polymer is apparently due to the formation of a three-dimensional structure during synthesis, while for the catalytic polymer this apparently occurs at the stage of its treatment.

AB - 1. The thermal and catalytic polymerization of dimethylbutadiyne leads to polymers that are readily oxidized by atmospheric oxygen. 2. As a result of polymerization, a block copolymer is formed, containing fragments of a substituted polyene and polyacene, together with a small amount of double bonds of the basic chain, isomerized into the side chain. 3. The insolubility of the thermal polymer is apparently due to the formation of a three-dimensional structure during synthesis, while for the catalytic polymer this apparently occurs at the stage of its treatment.

UR - http://www.scopus.com/inward/record.url?scp=34250477224&partnerID=8YFLogxK

U2 - 10.1007/BF00906492

DO - 10.1007/BF00906492

M3 - Article

AN - SCOPUS:34250477224

SN - 0568-5230

VL - 18

SP - 2268

EP - 2270

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 11

ER -

Structure of polymers of dimethylbutadiyne

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this