Structure of the thermal explosion limit

V. I. Babushok, V. M. Gol'dshtein

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

In a closed system an explosion limit is the transition region which separates the regions of slow and explosive reactions with respect to initial conditions. In the present paper the characteristic features of chemical reaction in the transition region are investigated for thermal explosion. The critical phase trajectory of the system contains an unstable integral manifold. Initial conditions corresponding to this trajectory can be understood as the explosion limit. An equation determining maximum temperature rise on the critical trajectory is obtained. The transition region can be divided into regions of slow and explosive transient regimes. The transition region is characterized by the extrema of induction period and degree of reactant consumption which correspond to a maximum reaction rate.

Original languageEnglish
Pages (from-to)221-224
Number of pages4
JournalCombustion and Flame
Volume72
Issue number3
DOIs
StatePublished - 1 Jan 1988
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)
  • Chemical Engineering (all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Physics and Astronomy (all)

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