STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS.

M. V. Landau; L. N. Alekseenko; B. K. Nefedov; G. D. Chukin; D. A. Agievskii; V. I. Kvashonkin; V. I. Mikhailov; S. A. Surin; L. I. Pavlova

STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS.

M. V. Landau, L. N. Alekseenko, B. K. Nefedov, G. D. Chukin, D. A. Agievskii, V. I. Kvashonkin, V. I. Mikhailov, S. A. Surin, L. I. Pavlova

Research output: Contribution to journal › Article › peer-review

Abstract

The catalytic activities of sulfidized Al-Ni-Mo catalysts, synthesized by different methods, were compared in the hydrogenation reaction of o-xylene, hydrode-sulfurization of thiophene, and hydrodenitrogenation of piperidine. It was found that irrespective of the method of the preparation of the catalysts, the hydrogenation of the aromatic ring preferentially proceeds on the sulfidation products of Ni and Mo compounds, weakly bound to the carrier (nickel isopolymolybdates and aluminomolybdates), removable by aqueous extraction, while the hydrogenolysis reactions of thiophene and piperidine are preferentially carried on the sulfidation products of compounds which are strongly bound to the carrier (of the surface aluminum molybdate and nickel aluminate type).

Original language	English
Pages (from-to)	379-385
Number of pages	7
Journal	Kinetics and Catalysis
Volume	27
Issue number	2 pt 2
State	Published - 1 Mar 1986
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Modeling and Simulation
Computer Science Applications

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Landau, M. V., Alekseenko, L. N., Nefedov, B. K., Chukin, G. D., Agievskii, D. A., Kvashonkin, V. I., Mikhailov, V. I., Surin, S. A., & Pavlova, L. I. (1986). STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS. Kinetics and Catalysis, 27(2 pt 2), 379-385.

Landau, M. V. ; Alekseenko, L. N. ; Nefedov, B. K. et al. / STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS. In: Kinetics and Catalysis. 1986 ; Vol. 27, No. 2 pt 2. pp. 379-385.

@article{6c1f96969bb84a608a2af9299a21700a,

title = "STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS.",

abstract = "The catalytic activities of sulfidized Al-Ni-Mo catalysts, synthesized by different methods, were compared in the hydrogenation reaction of o-xylene, hydrode-sulfurization of thiophene, and hydrodenitrogenation of piperidine. It was found that irrespective of the method of the preparation of the catalysts, the hydrogenation of the aromatic ring preferentially proceeds on the sulfidation products of Ni and Mo compounds, weakly bound to the carrier (nickel isopolymolybdates and aluminomolybdates), removable by aqueous extraction, while the hydrogenolysis reactions of thiophene and piperidine are preferentially carried on the sulfidation products of compounds which are strongly bound to the carrier (of the surface aluminum molybdate and nickel aluminate type).",

author = "Landau, {M. V.} and Alekseenko, {L. N.} and Nefedov, {B. K.} and Chukin, {G. D.} and Agievskii, {D. A.} and Kvashonkin, {V. I.} and Mikhailov, {V. I.} and Surin, {S. A.} and Pavlova, {L. I.}",

year = "1986",

month = mar,

day = "1",

language = "English",

volume = "27",

pages = "379--385",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "Pleiades Publishing",

number = "2 pt 2",

}

Landau, MV, Alekseenko, LN, Nefedov, BK, Chukin, GD, Agievskii, DA, Kvashonkin, VI, Mikhailov, VI, Surin, SA & Pavlova, LI 1986, 'STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS.', Kinetics and Catalysis, vol. 27, no. 2 pt 2, pp. 379-385.

STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS. / Landau, M. V.; Alekseenko, L. N.; Nefedov, B. K. et al.
In: Kinetics and Catalysis, Vol. 27, No. 2 pt 2, 01.03.1986, p. 379-385.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS.

AU - Landau, M. V.

AU - Alekseenko, L. N.

AU - Nefedov, B. K.

AU - Chukin, G. D.

AU - Agievskii, D. A.

AU - Kvashonkin, V. I.

AU - Mikhailov, V. I.

AU - Surin, S. A.

AU - Pavlova, L. I.

PY - 1986/3/1

Y1 - 1986/3/1

N2 - The catalytic activities of sulfidized Al-Ni-Mo catalysts, synthesized by different methods, were compared in the hydrogenation reaction of o-xylene, hydrode-sulfurization of thiophene, and hydrodenitrogenation of piperidine. It was found that irrespective of the method of the preparation of the catalysts, the hydrogenation of the aromatic ring preferentially proceeds on the sulfidation products of Ni and Mo compounds, weakly bound to the carrier (nickel isopolymolybdates and aluminomolybdates), removable by aqueous extraction, while the hydrogenolysis reactions of thiophene and piperidine are preferentially carried on the sulfidation products of compounds which are strongly bound to the carrier (of the surface aluminum molybdate and nickel aluminate type).

AB - The catalytic activities of sulfidized Al-Ni-Mo catalysts, synthesized by different methods, were compared in the hydrogenation reaction of o-xylene, hydrode-sulfurization of thiophene, and hydrodenitrogenation of piperidine. It was found that irrespective of the method of the preparation of the catalysts, the hydrogenation of the aromatic ring preferentially proceeds on the sulfidation products of Ni and Mo compounds, weakly bound to the carrier (nickel isopolymolybdates and aluminomolybdates), removable by aqueous extraction, while the hydrogenolysis reactions of thiophene and piperidine are preferentially carried on the sulfidation products of compounds which are strongly bound to the carrier (of the surface aluminum molybdate and nickel aluminate type).

UR - http://www.scopus.com/inward/record.url?scp=0022676662&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0022676662

SN - 0023-1584

VL - 27

SP - 379

EP - 385

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 2 pt 2

ER -

Landau MV, Alekseenko LN, Nefedov BK, Chukin GD, Agievskii DA, Kvashonkin VI et al. STUDY OF OXIDE PREDECESSORS OF ACTIVE STRUCTURES IN Al-Ni-Mo HYDROGENATION CATALYSTS BY EXTRACTIVE SEPARATION OF COMPONENTS. III. CATALYTIC ACTIVITY OF SULFIDATION PRODUCTS OF STRUCTURES STRONGLY AND WEAKLY BOUND TO THE CARRIER IN HYDROGENATION, HYDRODESULFURIZATION, AND HYDRODENTITROGENATION REACTIONS. Kinetics and Catalysis. 1986 Mar 1;27(2 pt 2):379-385.

Abstract

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