Studying the influence of synthesis conditions on the magnetic properties of perovskite-like YbFeO3 nanomaterials

Tran Dinh Trinh; Nguyen Anh Tien; Valentina Olegovna Mittova; Bui Ngoc Vy Phuong; Tran Thi Thu Ngan; Tran Thi To Nga; Nguyen Van My; Irina Yakovlevna Mittova; Elena Viktorovna Tomina; Le Thi Thanh Thuy; Thanh Son Cam

doi:10.1016/j.jssc.2023.124377

Studying the influence of synthesis conditions on the magnetic properties of perovskite-like YbFeO₃ nanomaterials

Tran Dinh Trinh
, Nguyen Anh Tien
, Valentina Olegovna Mittova
, Bui Ngoc Vy Phuong
, Tran Thi Thu Ngan
, Tran Thi To Nga
, Nguyen Van My
, Irina Yakovlevna Mittova
, Elena Viktorovna Tomina
, Le Thi Thanh Thuy
, Thanh Son Cam

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

By using the co-precipitation method, the orthorhombic structure of YbFeO₃ (o-YbFeO₃) was obtained. To investigate the effect of different synthesis conditions on the resulting samples, NaOH (SH) and (NH₄)₂CO₃ (AC) were used as precipitants, and a temperature range of 750–950 °C (t_c) was applied for calcining the as-synthesized products. Depending on the synthesis conditions, the samples can be monophasic or diphasic and exhibit crystalline structure distortion. As the t_c increases, the average size of o-YbFeO₃ crystallites increases, which is in the 30–60 nm range. The samples' magnetism was not significantly affected by the synthesis conditions, and all displayed paramagnetic behavior, as evidenced by low values of coercive force (0.02–150.01 Oe) and net magnetization (0.41–0.54 emu·g⁻¹); in this regard, the YbFeO₃-AC-850 sample appeared to be superior, and the oxygen element preferred to face the sample's surface. The sample's morphology consists of oval-spherical-like grains with high agglomeration.

Original language	English
Article number	124377
Journal	Journal of Solid State Chemistry
Volume	328
DOIs	https://doi.org/10.1016/j.jssc.2023.124377
State	Published - 1 Dec 2023
Externally published	Yes

Keywords

Co-precipitation synthesis
Functional property
Magnetic behavior
Perovskite
Ytterbium orthoferrite

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jssc.2023.124377

Cite this

Trinh, T. D., Tien, N. A., Mittova, V. O., Phuong, B. N. V., Ngan, T. T. T., Nga, T. T. T., Van My, N., Mittova, I. Y., Tomina, E. V., Thuy, L. T. T., & Cam, T. S. (2023). Studying the influence of synthesis conditions on the magnetic properties of perovskite-like YbFeO₃ nanomaterials. Journal of Solid State Chemistry, 328, Article 124377. https://doi.org/10.1016/j.jssc.2023.124377

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title = "Studying the influence of synthesis conditions on the magnetic properties of perovskite-like YbFeO3 nanomaterials",

abstract = "By using the co-precipitation method, the orthorhombic structure of YbFeO3 (o-YbFeO3) was obtained. To investigate the effect of different synthesis conditions on the resulting samples, NaOH (SH) and (NH4)2CO3 (AC) were used as precipitants, and a temperature range of 750–950 °C (tc) was applied for calcining the as-synthesized products. Depending on the synthesis conditions, the samples can be monophasic or diphasic and exhibit crystalline structure distortion. As the tc increases, the average size of o-YbFeO3 crystallites increases, which is in the 30–60 nm range. The samples' magnetism was not significantly affected by the synthesis conditions, and all displayed paramagnetic behavior, as evidenced by low values of coercive force (0.02–150.01 Oe) and net magnetization (0.41–0.54 emu·g−1); in this regard, the YbFeO3-AC-850 sample appeared to be superior, and the oxygen element preferred to face the sample's surface. The sample's morphology consists of oval-spherical-like grains with high agglomeration.",

keywords = "Co-precipitation synthesis, Functional property, Magnetic behavior, Perovskite, Ytterbium orthoferrite",

author = "Trinh, \{Tran Dinh\} and Tien, \{Nguyen Anh\} and Mittova, \{Valentina Olegovna\} and Phuong, \{Bui Ngoc Vy\} and Ngan, \{Tran Thi Thu\} and Nga, \{Tran Thi To\} and \{Van My\}, Nguyen and Mittova, \{Irina Yakovlevna\} and Tomina, \{Elena Viktorovna\} and Thuy, \{Le Thi Thanh\} and Cam, \{Thanh Son\}",

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doi = "10.1016/j.jssc.2023.124377",

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AU - Trinh, Tran Dinh

AU - Tien, Nguyen Anh

AU - Mittova, Valentina Olegovna

AU - Phuong, Bui Ngoc Vy

AU - Ngan, Tran Thi Thu

AU - Nga, Tran Thi To

AU - Van My, Nguyen

AU - Mittova, Irina Yakovlevna

AU - Tomina, Elena Viktorovna

AU - Thuy, Le Thi Thanh

AU - Cam, Thanh Son

PY - 2023/12/1

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N2 - By using the co-precipitation method, the orthorhombic structure of YbFeO3 (o-YbFeO3) was obtained. To investigate the effect of different synthesis conditions on the resulting samples, NaOH (SH) and (NH4)2CO3 (AC) were used as precipitants, and a temperature range of 750–950 °C (tc) was applied for calcining the as-synthesized products. Depending on the synthesis conditions, the samples can be monophasic or diphasic and exhibit crystalline structure distortion. As the tc increases, the average size of o-YbFeO3 crystallites increases, which is in the 30–60 nm range. The samples' magnetism was not significantly affected by the synthesis conditions, and all displayed paramagnetic behavior, as evidenced by low values of coercive force (0.02–150.01 Oe) and net magnetization (0.41–0.54 emu·g−1); in this regard, the YbFeO3-AC-850 sample appeared to be superior, and the oxygen element preferred to face the sample's surface. The sample's morphology consists of oval-spherical-like grains with high agglomeration.

AB - By using the co-precipitation method, the orthorhombic structure of YbFeO3 (o-YbFeO3) was obtained. To investigate the effect of different synthesis conditions on the resulting samples, NaOH (SH) and (NH4)2CO3 (AC) were used as precipitants, and a temperature range of 750–950 °C (tc) was applied for calcining the as-synthesized products. Depending on the synthesis conditions, the samples can be monophasic or diphasic and exhibit crystalline structure distortion. As the tc increases, the average size of o-YbFeO3 crystallites increases, which is in the 30–60 nm range. The samples' magnetism was not significantly affected by the synthesis conditions, and all displayed paramagnetic behavior, as evidenced by low values of coercive force (0.02–150.01 Oe) and net magnetization (0.41–0.54 emu·g−1); in this regard, the YbFeO3-AC-850 sample appeared to be superior, and the oxygen element preferred to face the sample's surface. The sample's morphology consists of oval-spherical-like grains with high agglomeration.

KW - Co-precipitation synthesis

KW - Functional property

KW - Magnetic behavior

KW - Perovskite

KW - Ytterbium orthoferrite

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