Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water

Mariana Marcos-Hernández; Roy A. Arrieta; Karen Ventura; José Hernández; Camilah D. Powell; Ariel J. Atkinson; Jasmina S. Markovski; Jorge Gardea-Torresdey; Kiril D. Hristovski; Paul Westerhoff; Michael S. Wong; Dino Villagrán

doi:10.1016/j.envadv.2021.100046

Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water

Mariana Marcos-Hernández, Roy A. Arrieta, Karen Ventura, José Hernández, Camilah D. Powell, Ariel J. Atkinson, Jasmina S. Markovski, Jorge Gardea-Torresdey, Kiril D. Hristovski, Paul Westerhoff, Michael S. Wong, Dino Villagrán

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A series of novel zeolitic imidazolate framework (ZIF) decorated superparamagnetic graphene oxide hybrid nanoadsorbents were synthesized, characterized, and tested for their As(III) adsorbed amount in simulated drinking water. The three composite nanomaterials are based each on three isostructural and water stable ZIFs, (C-1 based on ZIF-8, C-2 based on ZIF-67, and C-3 based on ZIF-Zn/Co). The composite nanomaterials and there parent materials were characterized through pXRD, TEM, FTIR, BET and magnetometry methods (SQUID), and were tested as adsorbents in a representative drinking water matrix containing arsenite (As(III)) at an initial trace concentration (realistic in some natural drinking water sources) of 35 µg/L. The nanoadsorbents were magnetically captured and removed after adsorption in batch conditions. Out of the three composites, C-2 shows the highest As(III) adsorbed amount at an initial concentration of 35 µg/L (q₀) of 202 µg/g, followed by C-3 with 102 µg/g and C-1 with 82 µg/g.

Original language	English
Article number	100046
Journal	Environmental Advances
Volume	4
DOIs	https://doi.org/10.1016/j.envadv.2021.100046
State	Published - 1 Jul 2021
Externally published	Yes

Keywords

Composite nanoadsorbents
Superparamagnetic
Trace arsenic removal
Zeolitic imidazolate frameworks

ASJC Scopus subject areas

Global and Planetary Change
Environmental Chemistry
Environmental Science (miscellaneous)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.envadv.2021.100046

Cite this

Marcos-Hernández, M., Arrieta, R. A., Ventura, K., Hernández, J., Powell, C. D., Atkinson, A. J., Markovski, J. S., Gardea-Torresdey, J., Hristovski, K. D., Westerhoff, P., Wong, M. S., & Villagrán, D. (2021). Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water. Environmental Advances, 4, Article 100046. https://doi.org/10.1016/j.envadv.2021.100046

@article{d9dc815a558d4a8eac38b02c26d44c8b,

title = "Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water",

abstract = "A series of novel zeolitic imidazolate framework (ZIF) decorated superparamagnetic graphene oxide hybrid nanoadsorbents were synthesized, characterized, and tested for their As(III) adsorbed amount in simulated drinking water. The three composite nanomaterials are based each on three isostructural and water stable ZIFs, (C-1 based on ZIF-8, C-2 based on ZIF-67, and C-3 based on ZIF-Zn/Co). The composite nanomaterials and there parent materials were characterized through pXRD, TEM, FTIR, BET and magnetometry methods (SQUID), and were tested as adsorbents in a representative drinking water matrix containing arsenite (As(III)) at an initial trace concentration (realistic in some natural drinking water sources) of 35 µg/L. The nanoadsorbents were magnetically captured and removed after adsorption in batch conditions. Out of the three composites, C-2 shows the highest As(III) adsorbed amount at an initial concentration of 35 µg/L (q0) of 202 µg/g, followed by C-3 with 102 µg/g and C-1 with 82 µg/g.",

keywords = "Composite nanoadsorbents, Superparamagnetic, Trace arsenic removal, Zeolitic imidazolate frameworks",

author = "Mariana Marcos-Hern{\'a}ndez and Arrieta, {Roy A.} and Karen Ventura and Jos{\'e} Hern{\'a}ndez and Powell, {Camilah D.} and Atkinson, {Ariel J.} and Markovski, {Jasmina S.} and Jorge Gardea-Torresdey and Hristovski, {Kiril D.} and Paul Westerhoff and Wong, {Michael S.} and Dino Villagr{\'a}n",

note = "Publisher Copyright: {\textcopyright} 2021",

year = "2021",

month = jul,

day = "1",

doi = "10.1016/j.envadv.2021.100046",

language = "English",

volume = "4",

journal = "Environmental Advances",

issn = "2666-7657",

publisher = "Elsevier",

}

TY - JOUR

T1 - Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water

AU - Marcos-Hernández, Mariana

AU - Arrieta, Roy A.

AU - Ventura, Karen

AU - Hernández, José

AU - Powell, Camilah D.

AU - Atkinson, Ariel J.

AU - Markovski, Jasmina S.

AU - Gardea-Torresdey, Jorge

AU - Hristovski, Kiril D.

AU - Westerhoff, Paul

AU - Wong, Michael S.

AU - Villagrán, Dino

PY - 2021/7/1

Y1 - 2021/7/1

N2 - A series of novel zeolitic imidazolate framework (ZIF) decorated superparamagnetic graphene oxide hybrid nanoadsorbents were synthesized, characterized, and tested for their As(III) adsorbed amount in simulated drinking water. The three composite nanomaterials are based each on three isostructural and water stable ZIFs, (C-1 based on ZIF-8, C-2 based on ZIF-67, and C-3 based on ZIF-Zn/Co). The composite nanomaterials and there parent materials were characterized through pXRD, TEM, FTIR, BET and magnetometry methods (SQUID), and were tested as adsorbents in a representative drinking water matrix containing arsenite (As(III)) at an initial trace concentration (realistic in some natural drinking water sources) of 35 µg/L. The nanoadsorbents were magnetically captured and removed after adsorption in batch conditions. Out of the three composites, C-2 shows the highest As(III) adsorbed amount at an initial concentration of 35 µg/L (q0) of 202 µg/g, followed by C-3 with 102 µg/g and C-1 with 82 µg/g.

AB - A series of novel zeolitic imidazolate framework (ZIF) decorated superparamagnetic graphene oxide hybrid nanoadsorbents were synthesized, characterized, and tested for their As(III) adsorbed amount in simulated drinking water. The three composite nanomaterials are based each on three isostructural and water stable ZIFs, (C-1 based on ZIF-8, C-2 based on ZIF-67, and C-3 based on ZIF-Zn/Co). The composite nanomaterials and there parent materials were characterized through pXRD, TEM, FTIR, BET and magnetometry methods (SQUID), and were tested as adsorbents in a representative drinking water matrix containing arsenite (As(III)) at an initial trace concentration (realistic in some natural drinking water sources) of 35 µg/L. The nanoadsorbents were magnetically captured and removed after adsorption in batch conditions. Out of the three composites, C-2 shows the highest As(III) adsorbed amount at an initial concentration of 35 µg/L (q0) of 202 µg/g, followed by C-3 with 102 µg/g and C-1 with 82 µg/g.

KW - Composite nanoadsorbents

KW - Superparamagnetic

KW - Trace arsenic removal

KW - Zeolitic imidazolate frameworks

UR - http://www.scopus.com/inward/record.url?scp=85118735736&partnerID=8YFLogxK

U2 - 10.1016/j.envadv.2021.100046

DO - 10.1016/j.envadv.2021.100046

M3 - Article

AN - SCOPUS:85118735736

SN - 2666-7657

VL - 4

JO - Environmental Advances

JF - Environmental Advances

M1 - 100046

ER -

Superparamagnetic nanoadsorbents for the removal of trace As(III) in drinking water

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this