Supersaturation, the spinodal, and their prediction using equations of state

Jaime Wisniak; Keren Galon

doi:10.1080/00319100008030312

Supersaturation, the spinodal, and their prediction using equations of state

Jaime Wisniak
, Keren Galon

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The equations of state of Redlich-Kwong, Soave, BWR, Schmidt-Wenzel, and Harmens-Knapp have been tested and compared in their ability to predict the spinodal and the experimental limits of superheat of pure liquids. The results indicate that only the Peng-Robinson, Soave and BWR equations are capable of predicting reduced kinetic limits of supersaturation above the experimental ones.

Original language	English
Pages (from-to)	643-661
Number of pages	19
Journal	Physics and Chemistry of Liquids
Volume	38
Issue number	6
DOIs	https://doi.org/10.1080/00319100008030312
State	Published - 1 Jan 2000

Keywords

Equations of state
Spinodal
Supersaturation

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00319100008030312

Cite this

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title = "Supersaturation, the spinodal, and their prediction using equations of state",

abstract = "The equations of state of Redlich-Kwong, Soave, BWR, Schmidt-Wenzel, and Harmens-Knapp have been tested and compared in their ability to predict the spinodal and the experimental limits of superheat of pure liquids. The results indicate that only the Peng-Robinson, Soave and BWR equations are capable of predicting reduced kinetic limits of supersaturation above the experimental ones.",

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AU - Galon, Keren

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N2 - The equations of state of Redlich-Kwong, Soave, BWR, Schmidt-Wenzel, and Harmens-Knapp have been tested and compared in their ability to predict the spinodal and the experimental limits of superheat of pure liquids. The results indicate that only the Peng-Robinson, Soave and BWR equations are capable of predicting reduced kinetic limits of supersaturation above the experimental ones.

AB - The equations of state of Redlich-Kwong, Soave, BWR, Schmidt-Wenzel, and Harmens-Knapp have been tested and compared in their ability to predict the spinodal and the experimental limits of superheat of pure liquids. The results indicate that only the Peng-Robinson, Soave and BWR equations are capable of predicting reduced kinetic limits of supersaturation above the experimental ones.

KW - Equations of state

KW - Spinodal

KW - Supersaturation

UR - https://www.scopus.com/pages/publications/0034351188

U2 - 10.1080/00319100008030312

DO - 10.1080/00319100008030312

M3 - Article

AN - SCOPUS:0034351188

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JO - Physics and Chemistry of Liquids

JF - Physics and Chemistry of Liquids

IS - 6

ER -

Supersaturation, the spinodal, and their prediction using equations of state

Abstract

Keywords

ASJC Scopus subject areas

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