Supramolecular polymorphism of the 1:1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

Andreas Lemmerer; Joel Bernstein; Mark A. Spackman

doi:10.1039/c1cc15849j

Supramolecular polymorphism of the 1:1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

Andreas Lemmerer, Joel Bernstein, Mark A. Spackman

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The tetrahedral arrangement of hydrogen bonding donor and acceptor groups is used to rationalise the design of a diamondoid network; however, a single proton transfer renders the four sites inequivalent, and results in two polymorphs of the title molecular salt utilizing similar intermolecular synthons.

Original language	English
Pages (from-to)	1883-1885
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	13
DOIs	https://doi.org/10.1039/c1cc15849j
State	Published - 16 Jan 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc15849j

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abstract = "The tetrahedral arrangement of hydrogen bonding donor and acceptor groups is used to rationalise the design of a diamondoid network; however, a single proton transfer renders the four sites inequivalent, and results in two polymorphs of the title molecular salt utilizing similar intermolecular synthons.",

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Supramolecular polymorphism of the 1:1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt. / Lemmerer, Andreas; Bernstein, Joel; Spackman, Mark A.
In: Chemical Communications, Vol. 48, No. 13, 16.01.2012, p. 1883-1885.

Research output: Contribution to journal › Article › peer-review

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T1 - Supramolecular polymorphism of the 1:1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

AU - Lemmerer, Andreas

AU - Bernstein, Joel

AU - Spackman, Mark A.

PY - 2012/1/16

Y1 - 2012/1/16

N2 - The tetrahedral arrangement of hydrogen bonding donor and acceptor groups is used to rationalise the design of a diamondoid network; however, a single proton transfer renders the four sites inequivalent, and results in two polymorphs of the title molecular salt utilizing similar intermolecular synthons.

AB - The tetrahedral arrangement of hydrogen bonding donor and acceptor groups is used to rationalise the design of a diamondoid network; however, a single proton transfer renders the four sites inequivalent, and results in two polymorphs of the title molecular salt utilizing similar intermolecular synthons.

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DO - 10.1039/c1cc15849j

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Supramolecular polymorphism of the 1:1 molecular salt (adamantane-1-carboxylate-3,5,7-tricarboxylic acid)·(hexamethylenetetraminium). A “failed” crystal engineering attempt

Abstract

ASJC Scopus subject areas

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