SURMOF induced polymorphism and crystal morphological engineering of acetaminophen polymorphs: Advantage of heterogeneous nucleation

Geetha Bolla; Allan S. Myerson

doi:10.1039/c8ce00272j

SURMOF induced polymorphism and crystal morphological engineering of acetaminophen polymorphs: Advantage of heterogeneous nucleation

Geetha Bolla, Allan S. Myerson

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13 Scopus citations

Abstract

Self-assembled monolayers are extended to SURMOFs as template hetero surfaces using a basic HKUST-1 MOF. The concept of MOF induced polymorphism with morphological engineering adapted to crystal engineering has shown to have the advantage of heterogeneous nucleation. The substrates are used to study the nucleation and growth of acetaminophen, and have resulted in metastable polymorphs which are of a desirable form with block morphology.

Original language	English
Pages (from-to)	2084-2088
Number of pages	5
Journal	CrystEngComm
Volume	20
Issue number	15
DOIs	https://doi.org/10.1039/c8ce00272j
State	Published - 1 Jan 2018
Externally published	Yes

ASJC Scopus subject areas

Chemistry (all)
Materials Science (all)
Condensed Matter Physics

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title = "SURMOF induced polymorphism and crystal morphological engineering of acetaminophen polymorphs: Advantage of heterogeneous nucleation",

abstract = "Self-assembled monolayers are extended to SURMOFs as template hetero surfaces using a basic HKUST-1 MOF. The concept of MOF induced polymorphism with morphological engineering adapted to crystal engineering has shown to have the advantage of heterogeneous nucleation. The substrates are used to study the nucleation and growth of acetaminophen, and have resulted in metastable polymorphs which are of a desirable form with block morphology.",

author = "Geetha Bolla and Myerson, {Allan S.}",

note = "Funding Information: GB and AM thank INDO-US for fellowship and Novartis for their financial support. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

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AU - Bolla, Geetha

AU - Myerson, Allan S.

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AB - Self-assembled monolayers are extended to SURMOFs as template hetero surfaces using a basic HKUST-1 MOF. The concept of MOF induced polymorphism with morphological engineering adapted to crystal engineering has shown to have the advantage of heterogeneous nucleation. The substrates are used to study the nucleation and growth of acetaminophen, and have resulted in metastable polymorphs which are of a desirable form with block morphology.

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SURMOF induced polymorphism and crystal morphological engineering of acetaminophen polymorphs: Advantage of heterogeneous nucleation

Abstract

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