Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Janice M. Rubin-Preminger; Joel Bernstein

doi:10.1002/hlca.200390246

Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Janice M. Rubin-Preminger, Joel Bernstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.

Original language	English
Pages (from-to)	3037-3054
Number of pages	18
Journal	Helvetica Chimica Acta
Volume	86
Issue number	9
DOIs	https://doi.org/10.1002/hlca.200390246
State	Published - 21 Oct 2003

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.",

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AB - The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.

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Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Abstract

ASJC Scopus subject areas

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