Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Janice M. Rubin-Preminger; Joel Bernstein

doi:10.1002/hlca.200390246

Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Janice M. Rubin-Preminger
, Joel Bernstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.

Original language	English
Pages (from-to)	3037-3054
Number of pages	18
Journal	Helvetica Chimica Acta
Volume	86
Issue number	9
DOIs	https://doi.org/10.1002/hlca.200390246
State	Published - 21 Oct 2003

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1002/hlca.200390246

Cite this

@article{4a41fe3e94224422aa5de30fd07e2782,

title = "Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid",

abstract = "The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.",

author = "Rubin-Preminger, \{Janice M.\} and Joel Bernstein",

year = "2003",

month = oct,

day = "21",

doi = "10.1002/hlca.200390246",

language = "English",

volume = "86",

pages = "3037--3054",

journal = "Helvetica Chimica Acta",

issn = "0018-019X",

publisher = "Wiley-Blackwell",

number = "9",

}

TY - JOUR

T1 - Surprises in a 'simple' system

T2 - 2,4-Diaminobenzenesulfonic acid

AU - Rubin-Preminger, Janice M.

AU - Bernstein, Joel

PY - 2003/10/21

Y1 - 2003/10/21

N2 - The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.

AB - The search for the polymorphic forms of 2,4-diaminobenzenesulfonic acid (DBSA), known to exist since 1880, has revealed a surprisingly rich solid-state system for such a simple molecule. A monohydrate, a dimoiric hydrate, an anhydrate and two polymorphic forms of the hydrochloride of this material have thus far been prepared. Their characterization by microscopic and thermal methods, FT-IR spectroscopy, and single-crystal structure determination are described.

UR - https://www.scopus.com/pages/publications/0141989683

U2 - 10.1002/hlca.200390246

DO - 10.1002/hlca.200390246

M3 - Article

AN - SCOPUS:0141989683

SN - 0018-019X

VL - 86

SP - 3037

EP - 3054

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 9

ER -

Surprises in a 'simple' system: 2,4-Diaminobenzenesulfonic acid

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this