Synthese und Kristallstruktur der spirocyclischen Gallium- Und Indium-Chalkogen-Heterocyclen [(Me 2Ga) 6S(SSiMe 3) 4], [(Me 2Ga) 6Se(SeSiMe 3) 4] und [(Me 2In) 6S(SSiMe 3) 4]

Oliver Kluge; Martin Puidokait; Ralf Biedermann; Harald Krautscheid

doi:10.1002/zaac.200700373

Synthese und Kristallstruktur der spirocyclischen Gallium- Und Indium-Chalkogen-Heterocyclen [(Me ₂Ga) ₆S(SSiMe ₃) ₄], [(Me ₂Ga) ₆Se(SeSiMe ₃) ₄] und [(Me ₂In) ₆S(SSiMe ₃) ₄]

Translated title of the contribution: Synthesis and crystal structures of spirocyclic gallium and indium chalcogen heterocycles [(Me ₂Ga) ₆S(SSiMe ₃) ₄], [(Me ₂Ga) ₆Se(SeSiMe ₃) ₄] and [(Me ₂In) ₆S(SSiMe ₃) ₄]

Oliver Kluge
, Martin Puidokait
, Ralf Biedermann
, Harald Krautscheid

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The isostructural title compounds [(Me ₂M) ₆E(ESiMe ₃) ₄] (M = Ga, In; E = S, Se) crystallize in space group C2/c and consist of two M ₃E ₃ rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M-CH ₃ and E-SiMe ₃ bonds can be used for further reactions.

Translated title of the contribution	Synthesis and crystal structures of spirocyclic gallium and indium chalcogen heterocycles [(Me ₂Ga) ₆S(SSiMe ₃) ₄], [(Me ₂Ga) ₆Se(SeSiMe ₃) ₄] and [(Me ₂In) ₆S(SSiMe ₃) ₄]
Original language	German
Pages (from-to)	2138-2140
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	633
Issue number	13-14
DOIs	https://doi.org/10.1002/zaac.200700373
State	Published - 5 Nov 2007
Externally published	Yes

Keywords

Chalcogen heterocycles
Crystal structures
Gallium
Indium

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200700373

Cite this

@article{86c1150d48ae44f9b3a9ac9551efd9fd,

title = "Synthese und Kristallstruktur der spirocyclischen Gallium- Und Indium-Chalkogen-Heterocyclen [(Me 2Ga) 6S(SSiMe 3) 4], [(Me 2Ga) 6Se(SeSiMe 3) 4] und [(Me 2In) 6S(SSiMe 3) 4]",

abstract = "The isostructural title compounds [(Me 2M) 6E(ESiMe 3) 4] (M = Ga, In; E = S, Se) crystallize in space group C2/c and consist of two M 3E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M-CH 3 and E-SiMe 3 bonds can be used for further reactions.",

keywords = "Chalcogen heterocycles, Crystal structures, Gallium, Indium",

author = "Oliver Kluge and Martin Puidokait and Ralf Biedermann and Harald Krautscheid",

year = "2007",

month = nov,

day = "5",

doi = "10.1002/zaac.200700373",

language = "גרמנית",

volume = "633",

pages = "2138--2140",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "13-14",

}

Synthese und Kristallstruktur der spirocyclischen Gallium- Und Indium-Chalkogen-Heterocyclen [(Me ₂Ga) ₆S(SSiMe ₃) ₄], [(Me ₂Ga) ₆Se(SeSiMe ₃) ₄] und [(Me ₂In) ₆S(SSiMe ₃) ₄]. / Kluge, Oliver; Puidokait, Martin; Biedermann, Ralf et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 633, No. 13-14, 05.11.2007, p. 2138-2140.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthese und Kristallstruktur der spirocyclischen Gallium- Und Indium-Chalkogen-Heterocyclen [(Me 2Ga) 6S(SSiMe 3) 4], [(Me 2Ga) 6Se(SeSiMe 3) 4] und [(Me 2In) 6S(SSiMe 3) 4]

AU - Kluge, Oliver

AU - Puidokait, Martin

AU - Biedermann, Ralf

AU - Krautscheid, Harald

PY - 2007/11/5

Y1 - 2007/11/5

N2 - The isostructural title compounds [(Me 2M) 6E(ESiMe 3) 4] (M = Ga, In; E = S, Se) crystallize in space group C2/c and consist of two M 3E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M-CH 3 and E-SiMe 3 bonds can be used for further reactions.

AB - The isostructural title compounds [(Me 2M) 6E(ESiMe 3) 4] (M = Ga, In; E = S, Se) crystallize in space group C2/c and consist of two M 3E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M-CH 3 and E-SiMe 3 bonds can be used for further reactions.

KW - Chalcogen heterocycles

KW - Crystal structures

KW - Gallium

KW - Indium

UR - https://www.scopus.com/pages/publications/35648970623

U2 - 10.1002/zaac.200700373

DO - 10.1002/zaac.200700373

M3 - מאמר

AN - SCOPUS:35648970623

SN - 0044-2313

VL - 633

SP - 2138

EP - 2140

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 13-14

ER -