Syntheses relevant to vitamin B12 biosynthesis: Synthesis of (±)faktor-I octamethyl ester

Simon P.D. Turner; Michael H. Block; Zhi Chu Sheng; Steven C. Zimmerman; Alan R. Battersby

doi:10.1039/C39850000583

Syntheses relevant to vitamin B₁₂ biosynthesis: Synthesis of (±)faktor-I octamethyl ester

Simon P.D. Turner, Michael H. Block, Zhi Chu Sheng, Steven C. Zimmerman, Alan R. Battersby

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Faktor-I, the chlorin which arises by aromatisation of the mono-C-methylated intermediate on the biosynthetic pathway to vitamin B₁₂, has been synthesised in racemic form as its octamethyl ester by ring-closing the macrocycle photochemically.

Original language	English
Pages (from-to)	583-585
Number of pages	3
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39850000583
State	Published - 1 Jan 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Syntheses relevant to vitamin B12 biosynthesis: Synthesis of (±)faktor-I octamethyl ester",

abstract = "Faktor-I, the chlorin which arises by aromatisation of the mono-C-methylated intermediate on the biosynthetic pathway to vitamin B12, has been synthesised in racemic form as its octamethyl ester by ring-closing the macrocycle photochemically.",

author = "Turner, {Simon P.D.} and Block, {Michael H.} and Sheng, {Zhi Chu} and Zimmerman, {Steven C.} and Battersby, {Alan R.}",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/C39850000583",

language = "English",

pages = "583--585",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

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T2 - Synthesis of (±)faktor-I octamethyl ester

AU - Turner, Simon P.D.

AU - Block, Michael H.

AU - Sheng, Zhi Chu

AU - Zimmerman, Steven C.

AU - Battersby, Alan R.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Faktor-I, the chlorin which arises by aromatisation of the mono-C-methylated intermediate on the biosynthetic pathway to vitamin B12, has been synthesised in racemic form as its octamethyl ester by ring-closing the macrocycle photochemically.

AB - Faktor-I, the chlorin which arises by aromatisation of the mono-C-methylated intermediate on the biosynthetic pathway to vitamin B12, has been synthesised in racemic form as its octamethyl ester by ring-closing the macrocycle photochemically.

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U2 - 10.1039/C39850000583

DO - 10.1039/C39850000583

M3 - Article

AN - SCOPUS:0021839338

SN - 0022-4936

SP - 583

EP - 585

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Syntheses relevant to vitamin B₁₂ biosynthesis: Synthesis of (±)faktor-I octamethyl ester

Abstract

ASJC Scopus subject areas

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