Interaction of TiCl4 and LiN(SiMe3)2 produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, TiIV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp3) 1.890(4) Å.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry