Synthesis and crystal structure of two titanasilazanes

Yu E. Ovehinnikov; M. V. Ustinov; V. A. Igonin; Yu T. Struchkov; I. D. Kalikhman; M. G. Voronkov

doi:10.1016/0022-328X(93)83276-2

Synthesis and crystal structure of two titanasilazanes

Yu E. Ovehinnikov, M. V. Ustinov, V. A. Igonin, Yu T. Struchkov, I. D. Kalikhman, M. G. Voronkov

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19 Scopus citations

Abstract

Interaction of TiCl₄ and LiN(SiMe₃)₂ produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, Ti^IV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp³) 1.890(4) Å.

Original language	English
Pages (from-to)	75-80
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	461
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)83276-2
State	Published - 30 Nov 1993
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(93)83276-2

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title = "Synthesis and crystal structure of two titanasilazanes",

abstract = "Interaction of TiCl4 and LiN(SiMe3)2 produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, TiIV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp3) 1.890(4) {\AA}.",

author = "Ovehinnikov, {Yu E.} and Ustinov, {M. V.} and Igonin, {V. A.} and Struchkov, {Yu T.} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1993",

month = nov,

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doi = "10.1016/0022-328X(93)83276-2",

language = "English",

volume = "461",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Synthesis and crystal structure of two titanasilazanes

AU - Ovehinnikov, Yu E.

AU - Ustinov, M. V.

AU - Igonin, V. A.

AU - Struchkov, Yu T.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1993/11/30

Y1 - 1993/11/30

N2 - Interaction of TiCl4 and LiN(SiMe3)2 produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, TiIV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp3) 1.890(4) Å.

AB - Interaction of TiCl4 and LiN(SiMe3)2 produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, TiIV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp3) 1.890(4) Å.

UR - http://www.scopus.com/inward/record.url?scp=0002466552&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(93)83276-2

DO - 10.1016/0022-328X(93)83276-2

M3 - Article

AN - SCOPUS:0002466552

SN - 0022-328X

VL - 461

SP - 75

EP - 80

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and crystal structure of two titanasilazanes

Abstract

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