Synthesis and crystal structure of two titanasilazanes

Yu E. Ovehinnikov, M. V. Ustinov, V. A. Igonin, Yu T. Struchkov, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journalArticlepeer-review

19 Scopus citations


Interaction of TiCl4 and LiN(SiMe3)2 produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, TiIV atoms are tetra-coordinated. Geometrical parameters of the centrosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: TiN 1.866-2.034(3), SiN(sp3) 1.890(4) Å.

Original languageEnglish
Pages (from-to)75-80
Number of pages6
JournalJournal of Organometallic Chemistry
Issue number1-2
StatePublished - 30 Nov 1993
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


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