Synthesis and Molecular Structure of Bis(cyclopentadienylcarbonylmanganese) Diphenylditellurium

A. A. Pasynskii; Yu V. Torubaev; I. L. Eremenko; E. V. Krasil'nikova; A. I. Yanovskii; Yu T. Struchkov

Synthesis and Molecular Structure of Bis(cyclopentadienylcarbonylmanganese) Diphenylditellurium

A. A. Pasynskii, Yu V. Torubaev, I. L. Eremenko, E. V. Krasil'nikova, A. I. Yanovskii, Yu T. Struchkov

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Dark violet crystals of trans-[CpMn(CO)₂]₂(μ-Ph₂Te₂) ₂ were obtained by a photochemical reaction Of CpMn(CO)₃ with Ph₂Te₂in tetrahydrofuran or heptane at 20°C. Based on X-ray structural data, in this compound, Mn atoms are bonded only through a diphenylditellurium bridge to form substantially shortened Mn-Te bonds (2.486(2) Å) and an elongated Te-Te bond (2.884(2) Å).

Original language	English
Pages (from-to)	648-651
Number of pages	4
Journal	Russian Journal of Inorganic Chemistry
Volume	42
Issue number	5
State	Published - 1 Jan 1997
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

@article{16108ae50c88408fb07b9a4880906113,

title = "Synthesis and Molecular Structure of Bis(cyclopentadienylcarbonylmanganese) Diphenylditellurium",

abstract = "Dark violet crystals of trans-[CpMn(CO)2]2(μ-Ph2Te2) 2 were obtained by a photochemical reaction Of CpMn(CO)3 with Ph2Te2in tetrahydrofuran or heptane at 20°C. Based on X-ray structural data, in this compound, Mn atoms are bonded only through a diphenylditellurium bridge to form substantially shortened Mn-Te bonds (2.486(2) {\AA}) and an elongated Te-Te bond (2.884(2) {\AA}).",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Eremenko, {I. L.} and Krasil'nikova, {E. V.} and Yanovskii, {A. I.} and Struchkov, {Yu T.}",

year = "1997",

month = jan,

day = "1",

language = "English",

volume = "42",

pages = "648--651",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "5",

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TY - JOUR

T1 - Synthesis and Molecular Structure of Bis(cyclopentadienylcarbonylmanganese) Diphenylditellurium

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Eremenko, I. L.

AU - Krasil'nikova, E. V.

AU - Yanovskii, A. I.

AU - Struchkov, Yu T.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Dark violet crystals of trans-[CpMn(CO)2]2(μ-Ph2Te2) 2 were obtained by a photochemical reaction Of CpMn(CO)3 with Ph2Te2in tetrahydrofuran or heptane at 20°C. Based on X-ray structural data, in this compound, Mn atoms are bonded only through a diphenylditellurium bridge to form substantially shortened Mn-Te bonds (2.486(2) Å) and an elongated Te-Te bond (2.884(2) Å).

AB - Dark violet crystals of trans-[CpMn(CO)2]2(μ-Ph2Te2) 2 were obtained by a photochemical reaction Of CpMn(CO)3 with Ph2Te2in tetrahydrofuran or heptane at 20°C. Based on X-ray structural data, in this compound, Mn atoms are bonded only through a diphenylditellurium bridge to form substantially shortened Mn-Te bonds (2.486(2) Å) and an elongated Te-Te bond (2.884(2) Å).

UR - http://www.scopus.com/inward/record.url?scp=2542583996&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2542583996

SN - 0036-0236

VL - 42

SP - 648

EP - 651

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 5

ER -

Synthesis and Molecular Structure of Bis(cyclopentadienylcarbonylmanganese) Diphenylditellurium

Abstract

ASJC Scopus subject areas

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