Synthesis and molecular structure of cyclopentadienyl(nitrosyl)(carbonyl) thiolate CpMn(CO)(NO)Sn(SPh)3 with a manganese-tin bond

A. A. Pasynskii; A. I. Blokhin; S. S. Shapovalov; Yu V. Torubaev

doi:10.1134/S0036023607060095

Synthesis and molecular structure of cyclopentadienyl(nitrosyl)(carbonyl) thiolate CpMn(CO)(NO)Sn(SPh)₃ with a manganese-tin bond

A. A. Pasynskii, A. I. Blokhin, S. S. Shapovalov, Yu V. Torubaev

Research output: Contribution to journal › Article › peer-review

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Abstract

The reaction of CpMn(CO)₂(NO)⁺Cl^- with tin dichloride gave a new ionic complex, CpMn(CO)₂(NO)⁺SnCl ₃ ^- , which was treated with an excess of sodium thiophenoxide. The resulting cyclopentadienyl nitrosyl carbonyl thiolate complex CpMn(CO)(NO)Sn(SPh)₃ containing a Sn(SPh)₃ ligand linked to manganese by a shortened Mn-Sn bond (2.533(2) Å) was structurally characterized.

Original language	English
Pages (from-to)	871-874
Number of pages	4
Journal	Russian Journal of Inorganic Chemistry
Volume	52
Issue number	6
DOIs	https://doi.org/10.1134/S0036023607060095
State	Published - 1 Jan 2007
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Synthesis and molecular structure of cyclopentadienyl(nitrosyl)(carbonyl) thiolate CpMn(CO)(NO)Sn(SPh)3 with a manganese-tin bond",

abstract = "The reaction of CpMn(CO)2(NO)+Cl- with tin dichloride gave a new ionic complex, CpMn(CO)2(NO)+SnCl 3 - , which was treated with an excess of sodium thiophenoxide. The resulting cyclopentadienyl nitrosyl carbonyl thiolate complex CpMn(CO)(NO)Sn(SPh)3 containing a Sn(SPh)3 ligand linked to manganese by a shortened Mn-Sn bond (2.533(2) {\AA}) was structurally characterized.",

author = "Pasynskii, {A. A.} and Blokhin, {A. I.} and Shapovalov, {S. S.} and Torubaev, {Yu V.}",

note = "Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Foundation for Basic Research, projects nos. 03-03-32730 and 06-03-32891.",

year = "2007",

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doi = "10.1134/S0036023607060095",

language = "English",

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journal = "Russian Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Synthesis and molecular structure of cyclopentadienyl(nitrosyl)(carbonyl) thiolate CpMn(CO)(NO)Sn(SPh)3 with a manganese-tin bond

AU - Pasynskii, A. A.

AU - Blokhin, A. I.

AU - Shapovalov, S. S.

AU - Torubaev, Yu V.

N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Foundation for Basic Research, projects nos. 03-03-32730 and 06-03-32891.

PY - 2007/1/1

Y1 - 2007/1/1

N2 - The reaction of CpMn(CO)2(NO)+Cl- with tin dichloride gave a new ionic complex, CpMn(CO)2(NO)+SnCl 3 - , which was treated with an excess of sodium thiophenoxide. The resulting cyclopentadienyl nitrosyl carbonyl thiolate complex CpMn(CO)(NO)Sn(SPh)3 containing a Sn(SPh)3 ligand linked to manganese by a shortened Mn-Sn bond (2.533(2) Å) was structurally characterized.

AB - The reaction of CpMn(CO)2(NO)+Cl- with tin dichloride gave a new ionic complex, CpMn(CO)2(NO)+SnCl 3 - , which was treated with an excess of sodium thiophenoxide. The resulting cyclopentadienyl nitrosyl carbonyl thiolate complex CpMn(CO)(NO)Sn(SPh)3 containing a Sn(SPh)3 ligand linked to manganese by a shortened Mn-Sn bond (2.533(2) Å) was structurally characterized.

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U2 - 10.1134/S0036023607060095

DO - 10.1134/S0036023607060095

M3 - Article

AN - SCOPUS:34547259443

SN - 0036-0236

VL - 52

SP - 871

EP - 874

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 6

ER -

Synthesis and molecular structure of cyclopentadienyl(nitrosyl)(carbonyl) thiolate CpMn(CO)(NO)Sn(SPh)₃ with a manganese-tin bond

Abstract

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