Synthesis and molecular structure of dithizonato(ethoxydicyclopentenyl) platinum(II)

A. A. Pasynskii; A. V. Romanenkov; Yu V. Torubaev; P. V. Belousov; K. A. Lysenko

Synthesis and molecular structure of dithizonato(ethoxydicyclopentenyl) platinum(II)

A. A. Pasynskii, A. V. Romanenkov, Yu V. Torubaev, P. V. Belousov, K. A. Lysenko

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The [(EtOC₁₀H₁₂)Pt(C₁₃H₁₁N ₄S)]·Et₂O (I) complex was synthesized by reacting [(EtOC₁₀H₁₂)PtOEt]₂ with dithizone, C ₁₃H₁₂N₄S. The complex was isolated from ether in the form of dichroic crystals and characterized by X-ray diffraction. The Pt(II) atom has a square-planar environment forming a σ bond Pt-C(9) (2.049 Å) and is π-coordinated to the double bond C(2)=C(3) (Pt-C, 2.151 and 2.196 Å) of an ethoxydicyclopentenyl group. This atom also forms a σ bond Pt-S (2.270 Å) and a donor-acceptor N → Pt bond (2.145 Å) with a dithizonato group.

Original language	English
Pages (from-to)	1842-1844
Number of pages	3
Journal	Russian Journal of Inorganic Chemistry
Volume	47
Issue number	12
State	Published - 1 Jan 2002
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

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title = "Synthesis and molecular structure of dithizonato(ethoxydicyclopentenyl) platinum(II)",

abstract = "The [(EtOC10H12)Pt(C13H11N 4S)]·Et2O (I) complex was synthesized by reacting [(EtOC10H12)PtOEt]2 with dithizone, C 13H12N4S. The complex was isolated from ether in the form of dichroic crystals and characterized by X-ray diffraction. The Pt(II) atom has a square-planar environment forming a σ bond Pt-C(9) (2.049 {\AA}) and is π-coordinated to the double bond C(2)=C(3) (Pt-C, 2.151 and 2.196 {\AA}) of an ethoxydicyclopentenyl group. This atom also forms a σ bond Pt-S (2.270 {\AA}) and a donor-acceptor N → Pt bond (2.145 {\AA}) with a dithizonato group.",

author = "Pasynskii, {A. A.} and Romanenkov, {A. V.} and Torubaev, {Yu V.} and Belousov, {P. V.} and Lysenko, {K. A.}",

year = "2002",

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language = "English",

volume = "47",

pages = "1842--1844",

journal = "Russian Journal of Inorganic Chemistry",

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publisher = "Pleiades Publishing",

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TY - JOUR

T1 - Synthesis and molecular structure of dithizonato(ethoxydicyclopentenyl) platinum(II)

AU - Pasynskii, A. A.

AU - Romanenkov, A. V.

AU - Torubaev, Yu V.

AU - Belousov, P. V.

AU - Lysenko, K. A.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The [(EtOC10H12)Pt(C13H11N 4S)]·Et2O (I) complex was synthesized by reacting [(EtOC10H12)PtOEt]2 with dithizone, C 13H12N4S. The complex was isolated from ether in the form of dichroic crystals and characterized by X-ray diffraction. The Pt(II) atom has a square-planar environment forming a σ bond Pt-C(9) (2.049 Å) and is π-coordinated to the double bond C(2)=C(3) (Pt-C, 2.151 and 2.196 Å) of an ethoxydicyclopentenyl group. This atom also forms a σ bond Pt-S (2.270 Å) and a donor-acceptor N → Pt bond (2.145 Å) with a dithizonato group.

AB - The [(EtOC10H12)Pt(C13H11N 4S)]·Et2O (I) complex was synthesized by reacting [(EtOC10H12)PtOEt]2 with dithizone, C 13H12N4S. The complex was isolated from ether in the form of dichroic crystals and characterized by X-ray diffraction. The Pt(II) atom has a square-planar environment forming a σ bond Pt-C(9) (2.049 Å) and is π-coordinated to the double bond C(2)=C(3) (Pt-C, 2.151 and 2.196 Å) of an ethoxydicyclopentenyl group. This atom also forms a σ bond Pt-S (2.270 Å) and a donor-acceptor N → Pt bond (2.145 Å) with a dithizonato group.

UR - http://www.scopus.com/inward/record.url?scp=8744293726&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:8744293726

SN - 0036-0236

VL - 47

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EP - 1844

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 12

ER -

Synthesis and molecular structure of dithizonato(ethoxydicyclopentenyl) platinum(II)

Abstract

ASJC Scopus subject areas

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