Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative

Alexander A. Pasynskii, Yury V. Torubaev, Alina Pavlova, Ivan V. Skabitsky, Gleb Denisov, Vitaly A. Grinberg

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A new chelating metalloligand (dppe)Pt(TeFc)2 (Fc = ferrocenyl) (1) was synthesized and used to prepare a mixed-metal tellurate-brigded complex (dppe)Pt(μ-TeFc)2Re(CO)3Cl (2). Both compounds were structurally and electrochemically investigated. Details of their molecular structure and CVA are discussed.

Original languageEnglish
Pages (from-to)247-255
Number of pages9
JournalJournal of Cluster Science
Volume26
Issue number1
DOIs
StatePublished - 1 Jan 2015
Externally publishedYes

Keywords

  • Cluster
  • Electrochemistry
  • Ferrocenyltelluride
  • Mixed-metal complexes
  • Platinum
  • Rhenium
  • X-ray analyses

ASJC Scopus subject areas

  • Biochemistry
  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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