Synthesis and molecular structure of the manganese cyclopentadienylnitrososulfide complexes CpMn(NO)(S5), [CpMn(NO)(S2)]2 and CpMn(NO)(S2CNEt 2)

A. A. Pasynskii; V. N. Grigor'ev; A. I. Blokhin; Yu V. Torubaev; K. A. Lysenko; V. V. Minin

Synthesis and molecular structure of the manganese cyclopentadienylnitrososulfide complexes CpMn(NO)(S₅), [CpMn(NO)(S₂)]₂ and CpMn(NO)(S₂CNEt ₂)

A. A. Pasynskii, V. N. Grigor'ev, A. I. Blokhin, Yu V. Torubaev, K. A. Lysenko, V. V. Minin

Research output: Contribution to journal › Article › peer-review

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Abstract

The paramagnetic mononuclear cyclopentadienylnitrosopentasulfide complex CpMn(NO)S₅ and the formally biradical diamagnetic binuclear cyclopentadienylnitrosodisulfide complex [CpMn(NO)(S₂)]₂ were synthesized as a result of treatment of [CpMn(CO)(NO)]₂ with an excess of elemental sulfur in boiling tetrahydrofuran. The diamagnetic complex CpMn(NO)(S₂CNEt₂) containing a manganese atom in a similar ligand environment was obtained by the interaction of [CpMn(CO) ₂(NO)]PF₆ with sodium diethyldithiocarbamate. The structure of the synthesized complexes was solved by X-ray crystallography.

Original language	English
Pages (from-to)	1346-1350
Number of pages	5
Journal	Russian Journal of Inorganic Chemistry
Volume	50
Issue number	9
State	Published - 1 Jan 2005
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

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title = "Synthesis and molecular structure of the manganese cyclopentadienylnitrososulfide complexes CpMn(NO)(S5), [CpMn(NO)(S2)]2 and CpMn(NO)(S2CNEt 2)",

abstract = "The paramagnetic mononuclear cyclopentadienylnitrosopentasulfide complex CpMn(NO)S5 and the formally biradical diamagnetic binuclear cyclopentadienylnitrosodisulfide complex [CpMn(NO)(S2)]2 were synthesized as a result of treatment of [CpMn(CO)(NO)]2 with an excess of elemental sulfur in boiling tetrahydrofuran. The diamagnetic complex CpMn(NO)(S2CNEt2) containing a manganese atom in a similar ligand environment was obtained by the interaction of [CpMn(CO) 2(NO)]PF6 with sodium diethyldithiocarbamate. The structure of the synthesized complexes was solved by X-ray crystallography.",

author = "Pasynskii, {A. A.} and Grigor'ev, {V. N.} and Blokhin, {A. I.} and Torubaev, {Yu V.} and Lysenko, {K. A.} and Minin, {V. V.}",

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TY - JOUR

T1 - Synthesis and molecular structure of the manganese cyclopentadienylnitrososulfide complexes CpMn(NO)(S5), [CpMn(NO)(S2)]2 and CpMn(NO)(S2CNEt 2)

AU - Pasynskii, A. A.

AU - Grigor'ev, V. N.

AU - Blokhin, A. I.

AU - Torubaev, Yu V.

AU - Lysenko, K. A.

AU - Minin, V. V.

PY - 2005/1/1

Y1 - 2005/1/1

N2 - The paramagnetic mononuclear cyclopentadienylnitrosopentasulfide complex CpMn(NO)S5 and the formally biradical diamagnetic binuclear cyclopentadienylnitrosodisulfide complex [CpMn(NO)(S2)]2 were synthesized as a result of treatment of [CpMn(CO)(NO)]2 with an excess of elemental sulfur in boiling tetrahydrofuran. The diamagnetic complex CpMn(NO)(S2CNEt2) containing a manganese atom in a similar ligand environment was obtained by the interaction of [CpMn(CO) 2(NO)]PF6 with sodium diethyldithiocarbamate. The structure of the synthesized complexes was solved by X-ray crystallography.

AB - The paramagnetic mononuclear cyclopentadienylnitrosopentasulfide complex CpMn(NO)S5 and the formally biradical diamagnetic binuclear cyclopentadienylnitrosodisulfide complex [CpMn(NO)(S2)]2 were synthesized as a result of treatment of [CpMn(CO)(NO)]2 with an excess of elemental sulfur in boiling tetrahydrofuran. The diamagnetic complex CpMn(NO)(S2CNEt2) containing a manganese atom in a similar ligand environment was obtained by the interaction of [CpMn(CO) 2(NO)]PF6 with sodium diethyldithiocarbamate. The structure of the synthesized complexes was solved by X-ray crystallography.

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M3 - Article

AN - SCOPUS:27344451533

SN - 0036-0236

VL - 50

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JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 9

ER -

Synthesis and molecular structure of the manganese cyclopentadienylnitrososulfide complexes CpMn(NO)(S₅), [CpMn(NO)(S₂)]₂ and CpMn(NO)(S₂CNEt ₂)

Abstract

ASJC Scopus subject areas

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