Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand

A. A. Pasynskii; Yu V. Torubaev; P. S. Kitaev; A. Yu Lyakina; K. A. Lysenko

Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand

A. A. Pasynskii, Yu V. Torubaev, P. S. Kitaev, A. Yu Lyakina, K. A. Lysenko

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A complex of monohydroxo-monothiolate-substituted acetylene was prepared by the reaction of CpMn(CO)₂[C₂(CH₂OH)₂] with tert-BuSH in the presence of aqueous HBF₄. This complex can react with W(CO)₅ · THF to give the heterometal complex CpMn(CO)₂[CH₂=CH(CO)CH₂SCMe ₃]W(CO)₄. According to X-ray diffraction, in this compound both the substitution of one OH group for a thiolate group and the alkyne isomerization into vinyl-keto-thiolate hydrocarbon take place, the manganese atom is coordinated to the terminal double C=C bond, and the tungsten atom is coordinated to the sulfur atom of the thiolate group and the oxygen atom of the keto group to give a five-membered intramolecular ring.

Original language	English
Pages (from-to)	46-49
Number of pages	4
Journal	Russian Journal of Inorganic Chemistry
Volume	45
Issue number	1
State	Published - 1 Jan 2000
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

@article{d07cf08a54c546ba87a245e4f2e93ac3,

title = "Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand",

abstract = "A complex of monohydroxo-monothiolate-substituted acetylene was prepared by the reaction of CpMn(CO)2[C2(CH2OH)2] with tert-BuSH in the presence of aqueous HBF4. This complex can react with W(CO)5 · THF to give the heterometal complex CpMn(CO)2[CH2=CH(CO)CH2SCMe 3]W(CO)4. According to X-ray diffraction, in this compound both the substitution of one OH group for a thiolate group and the alkyne isomerization into vinyl-keto-thiolate hydrocarbon take place, the manganese atom is coordinated to the terminal double C=C bond, and the tungsten atom is coordinated to the sulfur atom of the thiolate group and the oxygen atom of the keto group to give a five-membered intramolecular ring.",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Kitaev, {P. S.} and Lyakina, {A. Yu} and Lysenko, {K. A.}",

year = "2000",

month = jan,

day = "1",

language = "English",

volume = "45",

pages = "46--49",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "1",

}

Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand. / Pasynskii, A. A.; Torubaev, Yu V.; Kitaev, P. S. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 45, No. 1, 01.01.2000, p. 46-49.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Kitaev, P. S.

AU - Lyakina, A. Yu

AU - Lysenko, K. A.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - A complex of monohydroxo-monothiolate-substituted acetylene was prepared by the reaction of CpMn(CO)2[C2(CH2OH)2] with tert-BuSH in the presence of aqueous HBF4. This complex can react with W(CO)5 · THF to give the heterometal complex CpMn(CO)2[CH2=CH(CO)CH2SCMe 3]W(CO)4. According to X-ray diffraction, in this compound both the substitution of one OH group for a thiolate group and the alkyne isomerization into vinyl-keto-thiolate hydrocarbon take place, the manganese atom is coordinated to the terminal double C=C bond, and the tungsten atom is coordinated to the sulfur atom of the thiolate group and the oxygen atom of the keto group to give a five-membered intramolecular ring.

AB - A complex of monohydroxo-monothiolate-substituted acetylene was prepared by the reaction of CpMn(CO)2[C2(CH2OH)2] with tert-BuSH in the presence of aqueous HBF4. This complex can react with W(CO)5 · THF to give the heterometal complex CpMn(CO)2[CH2=CH(CO)CH2SCMe 3]W(CO)4. According to X-ray diffraction, in this compound both the substitution of one OH group for a thiolate group and the alkyne isomerization into vinyl-keto-thiolate hydrocarbon take place, the manganese atom is coordinated to the terminal double C=C bond, and the tungsten atom is coordinated to the sulfur atom of the thiolate group and the oxygen atom of the keto group to give a five-membered intramolecular ring.

UR - http://www.scopus.com/inward/record.url?scp=0042724391&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0042724391

SN - 0036-0236

VL - 45

SP - 46

EP - 49

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 1

ER -

Synthesis and Molecular Structure of the Manganese Tungsten Carbonyl Complex with an Isomerization Product of Monothiolate-Substituted 2-Butyne-1,4-diol as a Bridging Ligand

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this