Synthesis and molecular structures of Co2(CO)6-n(PPh3)n[μ-C 2(CH2R)2] (R=CH2OH or CH2SCMe3) derivatives containing chelated [CpFe(CO)2]2Sn or W(CO)4 fragments

A. A. Pasynskii; Y. V. Torubaev; F. S. Denisov; A. Y. Lyakina; R. I. Valiullina; G. G. Alexandrov; K. A. Lyssenko

doi:10.1016/S0022-328X(99)00706-8

Synthesis and molecular structures of Co₂(CO)_6-n(PPh₃)_n[μ-C ₂(CH₂R)₂] (R=CH₂OH or CH₂SCMe₃) derivatives containing chelated [CpFe(CO)₂]₂Sn or W(CO)₄ fragments

A. A. Pasynskii, Y. V. Torubaev, F. S. Denisov, A. Y. Lyakina, R. I. Valiullina, G. G. Alexandrov, K. A. Lyssenko

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Reaction of [Co₂(CO)₆][μ-C₂(CH₂OH) ₂] with [CpFe(CO)₂]₂Sn(OMe)₂ or interaction of [Co₂(CO)₅(PPh₃)][μ-C₂(CH ₂SCMe₃)₂] with W(CO)₅(THF) gives mixed-metal chelate derivatives [Co₂(CO)₆][μ-C₂(CH₂O) ₂]Sn[CpFe(CO)₂]₂ and [(Ph₃P)Co₂(CO)₅][μ-C₂(CH ₂SCMe₃)₂][W(CO)₄], respectively, characterized by X-ray diffraction analysis.

Original language	English
Pages (from-to)	196-199
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	597
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(99)00706-8
State	Published - 15 Mar 2000
Externally published	Yes

Keywords

Acetylene π-complex
Chelate
Cobalt
Iron
Mixed-metal cluster
Tin
Tungsten
X-ray analysis

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/S0022-328X(99)00706-8

Cite this

Pasynskii, A. A., Torubaev, Y. V., Denisov, F. S., Lyakina, A. Y., Valiullina, R. I., Alexandrov, G. G., & Lyssenko, K. A. (2000). Synthesis and molecular structures of Co₂(CO)_6-n(PPh₃)_n[μ-C ₂(CH₂R)₂] (R=CH₂OH or CH₂SCMe₃) derivatives containing chelated [CpFe(CO)₂]₂Sn or W(CO)₄ fragments. Journal of Organometallic Chemistry, 597(1-2), 196-199. https://doi.org/10.1016/S0022-328X(99)00706-8

@article{bddf686d23d84f8080797b77154dbef1,

title = "Synthesis and molecular structures of Co2(CO)6-n(PPh3)n[μ-C 2(CH2R)2] (R=CH2OH or CH2SCMe3) derivatives containing chelated [CpFe(CO)2]2Sn or W(CO)4 fragments",

abstract = "Reaction of [Co2(CO)6][μ-C2(CH2OH) 2] with [CpFe(CO)2]2Sn(OMe)2 or interaction of [Co2(CO)5(PPh3)][μ-C2(CH 2SCMe3)2] with W(CO)5(THF) gives mixed-metal chelate derivatives [Co2(CO)6][μ-C2(CH2O) 2]Sn[CpFe(CO)2]2 and [(Ph3P)Co2(CO)5][μ-C2(CH 2SCMe3)2][W(CO)4], respectively, characterized by X-ray diffraction analysis.",

keywords = "Acetylene π-complex, Chelate, Cobalt, Iron, Mixed-metal cluster, Tin, Tungsten, X-ray analysis",

author = "Pasynskii, {A. A.} and Torubaev, {Y. V.} and Denisov, {F. S.} and Lyakina, {A. Y.} and Valiullina, {R. I.} and Alexandrov, {G. G.} and Lyssenko, {K. A.}",

note = "Funding Information: This work is financially supported by INTAS (grant 96-1256) and the Russian Foundation of Fundamental Research (grants 97-03-33027 and 99-03-32806). ",

year = "2000",

month = mar,

day = "15",

doi = "10.1016/S0022-328X(99)00706-8",

language = "English",

volume = "597",

pages = "196--199",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Pasynskii, AA, Torubaev, YV, Denisov, FS, Lyakina, AY, Valiullina, RI, Alexandrov, GG & Lyssenko, KA 2000, 'Synthesis and molecular structures of Co₂(CO)_6-n(PPh₃)_n[μ-C ₂(CH₂R)₂] (R=CH₂OH or CH₂SCMe₃) derivatives containing chelated [CpFe(CO)₂]₂Sn or W(CO)₄ fragments', Journal of Organometallic Chemistry, vol. 597, no. 1-2, pp. 196-199. https://doi.org/10.1016/S0022-328X(99)00706-8

Synthesis and molecular structures of Co₂(CO)_6-n(PPh₃)_n[μ-C ₂(CH₂R)₂] (R=CH₂OH or CH₂SCMe₃) derivatives containing chelated [CpFe(CO)₂]₂Sn or W(CO)₄ fragments. / Pasynskii, A. A.; Torubaev, Y. V.; Denisov, F. S. et al.
In: Journal of Organometallic Chemistry, Vol. 597, No. 1-2, 15.03.2000, p. 196-199.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and molecular structures of Co2(CO)6-n(PPh3)n[μ-C 2(CH2R)2] (R=CH2OH or CH2SCMe3) derivatives containing chelated [CpFe(CO)2]2Sn or W(CO)4 fragments

AU - Pasynskii, A. A.

AU - Torubaev, Y. V.

AU - Denisov, F. S.

AU - Lyakina, A. Y.

AU - Valiullina, R. I.

AU - Alexandrov, G. G.

AU - Lyssenko, K. A.

N1 - Funding Information: This work is financially supported by INTAS (grant 96-1256) and the Russian Foundation of Fundamental Research (grants 97-03-33027 and 99-03-32806).

PY - 2000/3/15

Y1 - 2000/3/15

N2 - Reaction of [Co2(CO)6][μ-C2(CH2OH) 2] with [CpFe(CO)2]2Sn(OMe)2 or interaction of [Co2(CO)5(PPh3)][μ-C2(CH 2SCMe3)2] with W(CO)5(THF) gives mixed-metal chelate derivatives [Co2(CO)6][μ-C2(CH2O) 2]Sn[CpFe(CO)2]2 and [(Ph3P)Co2(CO)5][μ-C2(CH 2SCMe3)2][W(CO)4], respectively, characterized by X-ray diffraction analysis.

AB - Reaction of [Co2(CO)6][μ-C2(CH2OH) 2] with [CpFe(CO)2]2Sn(OMe)2 or interaction of [Co2(CO)5(PPh3)][μ-C2(CH 2SCMe3)2] with W(CO)5(THF) gives mixed-metal chelate derivatives [Co2(CO)6][μ-C2(CH2O) 2]Sn[CpFe(CO)2]2 and [(Ph3P)Co2(CO)5][μ-C2(CH 2SCMe3)2][W(CO)4], respectively, characterized by X-ray diffraction analysis.

KW - Acetylene π-complex

KW - Chelate

KW - Cobalt

KW - Iron

KW - Mixed-metal cluster

KW - Tin

KW - Tungsten

KW - X-ray analysis

UR - http://www.scopus.com/inward/record.url?scp=0042260469&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(99)00706-8

DO - 10.1016/S0022-328X(99)00706-8

M3 - Article

AN - SCOPUS:0042260469

SN - 0022-328X

VL - 597

SP - 196

EP - 199

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -