Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands

A. A. Pasynskii; I. V. Skabitsky; Yu V. Torubaev; V. A. Grinberg

doi:10.1134/S1070328413040088

Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands

A. A. Pasynskii, I. V. Skabitsky, Yu V. Torubaev, V. A. Grinberg

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Interaction of [Cp₂Cr₂(CO)₄[μ-SC ₅H₄Mn(CO)₃]₂ with sulphur gave binuclear complex Cp₂Cr₂[μ-SC₅H ₄Mn(CO)₃]₂(μ-S) (I) (Cp = π-C ₅H₅) and triangular cluster Cp₃Cr ₃[μ-SC₅H₄Mn(CO)₃](μ-S) ₂(μ₃-S) (II). I was also synthesized from Cp ₂Cr₂(μ-SCMe₃)₂(μ-S) and (CO)₃Mn(C₅H₄SH). Interaction between I and Co₂(CO)₈ resulted in triangular mixed-metal cluster Cp₂Cr₂[μ-SC₅H₄Mn(CO) ₃](μ³-S)₂Co(CO)₂ (III). The molecular structures of I-III were determined by means of single-crystal X-ray diffraction analysis.

Original language	English
Pages (from-to)	305-311
Number of pages	7
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	39
Issue number	4
DOIs	https://doi.org/10.1134/S1070328413040088
State	Published - 7 Jun 2013
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands",

abstract = "Interaction of [Cp2Cr2(CO)4[μ-SC 5H4Mn(CO)3]2 with sulphur gave binuclear complex Cp2Cr2[μ-SC5H 4Mn(CO)3]2(μ-S) (I) (Cp = π-C 5H5) and triangular cluster Cp3Cr 3[μ-SC5H4Mn(CO)3](μ-S) 2(μ3-S) (II). I was also synthesized from Cp 2Cr2(μ-SCMe3)2(μ-S) and (CO)3Mn(C5H4SH). Interaction between I and Co2(CO)8 resulted in triangular mixed-metal cluster Cp2Cr2[μ-SC5H4Mn(CO) 3](μ3-S)2Co(CO)2 (III). The molecular structures of I-III were determined by means of single-crystal X-ray diffraction analysis.",

author = "Pasynskii, {A. A.} and Skabitsky, {I. V.} and Torubaev, {Yu V.} and Grinberg, {V. A.}",

note = "Funding Information: RAS) for X ray diffraction investigations. This work is financially supported by Grant of President of Russian Federation (MD 7122.2012.3), Russian Foundation of Fundamental Research (grants nos. 12 03 00860, 12 03 33101, 12 03 12002), Presidium of RAS (grant no. 8P21) and Dep. Of Chemistry and Material Sci ences RAS (grant no. OKh1.3).",

year = "2013",

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doi = "10.1134/S1070328413040088",

language = "English",

volume = "39",

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journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands. / Pasynskii, A. A.; Skabitsky, I. V.; Torubaev, Yu V. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 39, No. 4, 07.06.2013, p. 305-311.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands

AU - Pasynskii, A. A.

AU - Skabitsky, I. V.

AU - Torubaev, Yu V.

AU - Grinberg, V. A.

N1 - Funding Information: RAS) for X ray diffraction investigations. This work is financially supported by Grant of President of Russian Federation (MD 7122.2012.3), Russian Foundation of Fundamental Research (grants nos. 12 03 00860, 12 03 33101, 12 03 12002), Presidium of RAS (grant no. 8P21) and Dep. Of Chemistry and Material Sci ences RAS (grant no. OKh1.3).

PY - 2013/6/7

Y1 - 2013/6/7

N2 - Interaction of [Cp2Cr2(CO)4[μ-SC 5H4Mn(CO)3]2 with sulphur gave binuclear complex Cp2Cr2[μ-SC5H 4Mn(CO)3]2(μ-S) (I) (Cp = π-C 5H5) and triangular cluster Cp3Cr 3[μ-SC5H4Mn(CO)3](μ-S) 2(μ3-S) (II). I was also synthesized from Cp 2Cr2(μ-SCMe3)2(μ-S) and (CO)3Mn(C5H4SH). Interaction between I and Co2(CO)8 resulted in triangular mixed-metal cluster Cp2Cr2[μ-SC5H4Mn(CO) 3](μ3-S)2Co(CO)2 (III). The molecular structures of I-III were determined by means of single-crystal X-ray diffraction analysis.

AB - Interaction of [Cp2Cr2(CO)4[μ-SC 5H4Mn(CO)3]2 with sulphur gave binuclear complex Cp2Cr2[μ-SC5H 4Mn(CO)3]2(μ-S) (I) (Cp = π-C 5H5) and triangular cluster Cp3Cr 3[μ-SC5H4Mn(CO)3](μ-S) 2(μ3-S) (II). I was also synthesized from Cp 2Cr2(μ-SCMe3)2(μ-S) and (CO)3Mn(C5H4SH). Interaction between I and Co2(CO)8 resulted in triangular mixed-metal cluster Cp2Cr2[μ-SC5H4Mn(CO) 3](μ3-S)2Co(CO)2 (III). The molecular structures of I-III were determined by means of single-crystal X-ray diffraction analysis.

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Synthesis and molecular structures of cyclopentadienyl sulfide complexes of chromium with cymantrenyl-thiolate bridging ligands

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